Characterization of CoOZnO solid solutions
作者： F. Pepe , M. Schiavello , G. Ferraris
DOI: 10.1016/0022-4596(75)90178-4
关键词:
摘要: Abstract Lattice parameters, magnetic susceptibilities (over the temperature range 98–298°K) and reflectance spectra (uv visible) of solid solutions CoOZnO up to 10% M CoO have been studied. It is shown that true solution achieved Co 2+ ions substitute Zn in tetrahedral positions. The effect addition increase a parameter decrease c ratio. moment has found be 4.54 ± 0.05 μ B by extrapolation. A discussion structural data terms presence C 3 v effective symmetry given.
harvard.edu
elsevier.com
sci-hub.se 参考文章(18)
Brian N Figgis, Introduction to ligand fields Published in <b>1966</b> in New York NY) by Interscience. ,(1966)
Richard H. Holm, F. Albert Cotton, Magnetic Investigations of Spin‐Free Cobaltous Complexes. II. Tetrahedral Complexes Journal of Chemical Physics. ,vol. 32, pp. 1168- 1172 ,(1960) , 10.1063/1.1730868
P. Cossee, A.E. Van Arkel, Magnetic properties of Co2+ ions in tetrahedral interstices of an oxide lattice Journal of Physics and Chemistry of Solids. ,vol. 15, pp. 1- 6 ,(1960) , 10.1016/0022-3697(60)90092-5
C.H. Bates, W.B. White, R. Roy, The solubility of transition metal oxides in zinc oxide and the reflectance spectra of Mn2+ and Fe2+ in tetrahedral fields Journal of Inorganic and Nuclear Chemistry. ,vol. 28, pp. 397- 405 ,(1966) , 10.1016/0022-1902(66)80318-4
M.Lo Jacono, P. Porta, A. Cimino, An X-ray and magnetic investigation of solubility of NiO in ZnO Journal of Solid State Chemistry. ,vol. 3, pp. 501- 504 ,(1971) , 10.1016/0022-4596(71)90092-2
A. Navrotsky, O.J. Kleppa, The thermodynamics of cation distributions in simple spinels Journal of Inorganic and Nuclear Chemistry. ,vol. 29, pp. 2701- 2714 ,(1967) , 10.1016/0022-1902(67)80008-3
F. A. Cotton, D. M. L. Goodgame, M. Goodgame, The Electronic Structures of Tetrahedral Cobalt(II) Complexes Journal of the American Chemical Society. ,vol. 83, pp. 4690- 4699 ,(1961) , 10.1021/JA01484A002
Donald S. McClure, The distribution of transition metal cations in spinels Journal of Physics and Chemistry of Solids. ,vol. 3, pp. 311- 317 ,(1957) , 10.1016/0022-3697(57)90034-3
Herbert A. Weakliem, Optical Spectra of Ni2+, Co2+, and Cu2+in Tetrahedral Sites in Crystals The Journal of Chemical Physics. ,vol. 36, pp. 2117- 2140 ,(1962) , 10.1063/1.1732840
J. Ferguson, Crystal‐Field Spectra of d3,7 Ions. I. Electronic Absorption Spectrum of CoCl4= in Three Crystalline Environments The Journal of Chemical Physics. ,vol. 39, pp. 116- 128 ,(1963) , 10.1063/1.1733987