Construction of a square-planar hydroperoxo-copper(II) complex inducing a higher catalytic reactivity
作者： Tatsuya Fujii , Asako Naito , Syuhei Yamaguchi , Akira Wada , Yasuhiro Funahashi
DOI: 10.1039/B308073K
关键词:
摘要: A novel hydroperoxo-copper(II) complex with a square-planar geometry has been prepared, which exhibited higher selectivity and catalytic reactivity for dimethyl sulfide, in contrast to that trigonal-bipyramidal one.
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sci-hub.se 参考文章(15)
T.M. Pettingill, R.W. Strange, N.J. Blackburn, Carbonmonoxy dopamine beta-hydroxylase. Structural characterization by Fourier transform infrared, fluorescence, and x-ray absorption spectroscopy. Journal of Biological Chemistry. ,vol. 266, pp. 16996- 17003 ,(1991) , 10.1016/S0021-9258(19)47331-6
T M Pettingill, N J Blackburn, R T Shigeta, K S Seagraves, Characterization of a carbon monoxide complex of reduced dopamine beta-hydroxylase. Evidence for inequivalence of the Cu(I) centers. Journal of Biological Chemistry. ,vol. 265, pp. 15383- 15386 ,(1990) , 10.1016/S0021-9258(18)55407-7
N.J. Blackburn, S.S. Hasnain, T.M. Pettingill, R.W. Strange, Copper K-extended x-ray absorption fine structure studies of oxidized and reduced dopamine beta-hydroxylase. Confirmation of a sulfur ligand to copper(I) in the reduced enzyme. Journal of Biological Chemistry. ,vol. 266, pp. 23120- 23127 ,(1991) , 10.1016/S0021-9258(18)54471-9
Judith P. Klinman, Mechanisms Whereby Mononuclear Copper Proteins Functionalize Organic Substrates. Chemical Reviews. ,vol. 96, pp. 2541- 2562 ,(1996) , 10.1021/CR950047G
Jelle Brinksma, René La Crois, Ben L Feringa, Maria Irene Donnoli, Carlo Rosini, New ligands for manganese catalysed selective oxidation of sulfides to sulfoxides with hydrogen peroxide Tetrahedron Letters. ,vol. 42, pp. 4049- 4052 ,(2001) , 10.1016/S0040-4039(01)00626-8
S. T. Prigge, Amidation of Bioactive Peptides: The Structure of Peptidylglycine -Hydroxylating Monooxygenase Science. ,vol. 278, pp. 1300- 1305 ,(1997) , 10.1126/SCIENCE.278.5341.1300
Leslie C. Stewart, Judith P. Klinman, Dopamine beta-hydroxylase of adrenal chromaffin granules: structure and function. Annual Review of Biochemistry. ,vol. 57, pp. 551- 592 ,(1988) , 10.1146/ANNUREV.BI.57.070188.003003
Peng Chen, Kiyoshi Fujisawa, Edward I. Solomon, Spectroscopic and Theoretical Studies of Mononuclear Copper(II) Alkyl- and Hydroperoxo Complexes: Electronic Structure Contributions to Reactivity Journal of the American Chemical Society. ,vol. 122, pp. 10177- 10193 ,(2000) , 10.1021/JA0016755
Betty A. Eipper, Andrew S. W. Quon, Richard E. Mains, John S. Boswell, Ninian J. Blackburn, The catalytic core of peptidylglycine alpha-hydroxylating monooxygenase: investigation by site-directed mutagenesis, Cu X-ray absorption spectroscopy, and electron paramagnetic resonance. Biochemistry. ,vol. 34, pp. 2857- 2865 ,(1995) , 10.1021/BI00009A016
Masahito Kodera, Toshio Kita, Izumi Miura, Noritoshi Nakayama, Tomohisa Kawata, Koji Kano, Shun Hirota, Hydroperoxo−Copper(II) Complex Stabilized by N3S-Type Ligand Having a Phenyl Thioether Journal of the American Chemical Society. ,vol. 123, pp. 7715- 7716 ,(2001) , 10.1021/JA010689N