Core–Shell Composites Based on Multiwalled Carbon Nanotubes and Cesium Tungsten Bronze to Realize Charge Transport Balance for Photocatalytic Water Oxidation

作者: Yingqiang Zhao , Fengyun Han , Qian Wang , Guan-Wei Cui , Xi-Feng Shi

DOI: 10.1002/CCTC.201501072

关键词:

摘要: Core–shell composite photocatalysts based on multiwalled carbon nanotubes (MWCNTs) and Cs2W3O10 are first synthesized by an ion-directing method. Cs+ is preadsorbed the surface of MWCNTs electrostatic forces directs crystallization to form a uniform layer MWCNTs. This core–shell arrangement MWCNT@Cs2W3O10 photocatalyst with 15 nm thick allows charge transport balance be achieved in photocatalytic water oxidation process confers high photoactivity. Other reference that deviate from this result deteriorated The established synthetic method provides new for design synthesis photocatalysts, realization helpful understand nature enhancement photoactivity processes.

参考文章(26)
Burak Derkus, Kaan Cebesoy Emregul, Emel Emregul, Evaluation of protein immobilization capacity on various carbon nanotube embedded hydrogel biomaterials. Materials Science and Engineering: C. ,vol. 56, pp. 132- 140 ,(2015) , 10.1016/J.MSEC.2015.06.022
Yanhong Yin, Chun′an Ma, Ziping Wu, Man Zhao, Litao Chen, Youqun Chu, Synthesis and Characterization of Sphere-like Pt Nanoparticles Supported on DWCNT/WO3 Nanorods with Electrocatalytic Activity Journal of Materials Science & Technology. ,vol. 31, pp. 888- 894 ,(2015) , 10.1016/J.JMST.2014.09.023
Jincheng Liu, Olivier Margeat, Walid Dachraoui, Xianjie Liu, Mats Fahlman, Jorg Ackermann, Gram‐Scale Synthesis of Ultrathin Tungsten Oxide Nanowires and their Aspect Ratio‐Dependent Photocatalytic Activity Advanced Functional Materials. ,vol. 24, pp. 6029- 6037 ,(2014) , 10.1002/ADFM.201401261
David James Martin, Philip James Thomas Reardon, Savio J. A. Moniz, Junwang Tang, Visible Light-Driven Pure Water Splitting by a Nature-Inspired Organic Semiconductor-Based System Journal of the American Chemical Society. ,vol. 136, pp. 12568- 12571 ,(2014) , 10.1021/JA506386E
Lei Wang, Jinhua Zhan, Weiliu Fan, Guanwei Cui, Honggang Sun, Linhai Zhuo, Xian Zhao, Bo Tang, Microcrystalline sodium tungsten bronze nanowire bundles as efficient visible light-responsive photocatalysts. Chemical Communications. ,vol. 46, pp. 8833- 8835 ,(2010) , 10.1039/C0CC03660A
Katherine Villa, Sebastián Murcia-López, Teresa Andreu, Joan Ramón Morante, Mesoporous WO3 photocatalyst for the partial oxidation of methane to methanol using electron scavengers Applied Catalysis B-environmental. ,vol. 163, pp. 150- 155 ,(2015) , 10.1016/J.APCATB.2014.07.055
Xianghui Zhang, Xihong Lu, Yongqi Shen, Jingbin Han, Longyan Yuan, Li Gong, Zhi Xu, Xuedong Bai, Min Wei, Yexiang Tong, Yihua Gao, Jian Chen, Jun Zhou, Zhong Lin Wang, Three-dimensional WO3 nanostructures on carbon paper: photoelectrochemical property and visible light driven photocatalysis. Chemical Communications. ,vol. 47, pp. 5804- 5806 ,(2011) , 10.1039/C1CC10389J
Wei Cheng, Yanrui Ju, Payam Payamyar, Darinka Primc, Jingyi Rao, Christoph Willa, Dorota Koziej, Markus Niederberger, Großflächige Anordnung von Wolframoxidnanodrähten auf ebenen und strukturierten Substraten für Gassensorik bei Raumtemperatur Angewandte Chemie. ,vol. 127, pp. 347- 351 ,(2015) , 10.1002/ANGE.201408617
Gang Liu, Jingfeng Han, Xin Zhou, Lei Huang, Fuxiang Zhang, Xiuli Wang, Chunmei Ding, Xiaojia Zheng, Hongxian Han, Can Li, Enhancement of visible-light-driven O2 evolution from water oxidation on WO3 treated with hydrogen Journal of Catalysis. ,vol. 307, pp. 148- 152 ,(2013) , 10.1016/J.JCAT.2013.06.024