Electron beam radiation curing of natural rubber filled with silica-graphene mixture prepared by latex mixing

作者: Worawat Jansomboon , Surapich Loykulnant , Paisan Kongkachuichay , Peerapan Dittanet , Paweena Prapainainar

DOI: 10.1016/J.INDCROP.2019.111789

关键词:

摘要: Abstract The mechanical properties of irradiated natural rubber (NR) composites filled with silica (SiO2) and graphene nanoplatelets (GE) mixture have not been studied sufficiently for more understanding since they are interesting composites. SiO2/GE produced by mixing method were added to NR latex mixing. products subsequently cured EB irradiation form Filler content (1, 2.5 5 phr), the proportion GE in fillers (0.008%, 0.056%, 3.23% 14.29%), dose (100, 150, 200 250 kGy) varied these results EDXS elemental mapping confirmed presence filler, while FTIR that no new functional groups occurred between SiO2 GE. Mechanical thermal investigated. Scanning electron microscope (SEM) indicated good dispersion matrix. showed could be used as a mean crosslinking improve their tensile properties. phr SiO2/0.056%GE an 150 kGy (NR/SiO2/0.056%GE-EB) highest strength, well acceptable moduli at 100, 300, 500% strain. tear strength was higher than only (NR/SiO2-EB), (NR/GE-EB) equivalent amount using same greatly strength. It found high (3.23% or higher) lowered effect curing step on also comparison one-time two-times crosslink density increased when repeating increasing kGy, which impacted negatively movement molecular chain, resulting negative Thermogravimetric analysis there small improvement stability NR/SiO2/0.056%GE-EB compared NR-EB. Moreover, degradation temperature (Td) decreased applying doses composite. Therefore, individual filler hybrid

参考文章(56)
Peter A. Ciullo, Norman Hewitt, The rubber formulary ,(1999)
A. Whelan, K. S. Lee, Developments in Rubber Technology ,(1979)
Dimitrios G. Papageorgiou, Ian A. Kinloch, Robert J. Young, Graphene/elastomer nanocomposites Carbon. ,vol. 95, pp. 460- 484 ,(2015) , 10.1016/J.CARBON.2015.08.055
Wang Xing, Jinrong Wu, Guangsu Huang, Hui Li, Maozhu Tang, Xuan Fu, Enhanced mechanical properties of graphene/natural rubber nanocomposites at low content Polymer International. ,vol. 63, pp. 1674- 1681 ,(2014) , 10.1002/PI.4689
Frederick R. Eirich, Science and Technology of Rubber ,(2012)
Isaac O. Igwe, Obumneme E. Ezeani, Studies on the Transport of Aromatic Solvents through Filled Natural Rubber International Journal of Polymer Science. ,vol. 2012, pp. 1- 11 ,(2012) , 10.1155/2012/212507
Andrzej G. Chmielewski, Mohammad Haji-Saeid, Shamshad Ahmed, Progress in radiation processing of polymers Nuclear Instruments & Methods in Physics Research Section B-beam Interactions With Materials and Atoms. ,vol. 236, pp. 44- 54 ,(2005) , 10.1016/J.NIMB.2005.03.247
Hailan Kang, Kanghua Zuo, Zhao Wang, Liqun Zhang, Li Liu, Baochun Guo, Using a green method to develop graphene oxide/elastomers nanocomposites with combination of high barrier and mechanical performance Composites Science and Technology. ,vol. 92, pp. 1- 8 ,(2014) , 10.1016/J.COMPSCITECH.2013.12.004
Geoffrey Gee, Tensile strengths of pure gum natural rubber compounds Journal of Polymer Science. ,vol. 2, pp. 451- 462 ,(1947) , 10.1002/POL.1947.120020501
Bulent Ozbas, Shigeyuki Toki, Benjamin S. Hsiao, Benjamin Chu, Richard A. Register, Ilhan A. Aksay, Robert K. Prud'homme, Douglas H. Adamson, Strain-induced crystallization and mechanical properties of functionalized graphene sheet-filled natural rubber Journal of Polymer Science Part B: Polymer Physics. ,vol. 50, pp. 718- 723 ,(2012) , 10.1002/POLB.23060