High-temperature solar thermal processing Zn(s) and CO from ZnO(s) and C(gr) using Ti2O3(s) and TiO2(s)
作者： R.D. Palumbo , M.B. Campbell , T.H. Grafe
DOI: 10.1016/0360-5442(92)90067-A
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摘要: Abstract An analytical model of a two-step solar process that produces Zn(s) and CO from ZnO(s) C(gr) is presented. The occurs in two steps according to the following reaction scheme: Ti2O3(s) + → Zn 2TiO2(s) (low temperature), (high temperature). We demonstrate theoretical effects operating conditions on performance. reactions were also studied experimentally. produced with first an electric furnace temperature range 900–1275 K 1 atm Ar. second related ones performed furnace. higher TiNO2N−1(s) formed at temperatures between 1675 2175 K. These oxides react produce Zn(s). Some our experiences experimental techniques are described.
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