Novel K3V2(PO4)3/C Bundled Nanowires as Superior Sodium-Ion Battery Electrode with Ultrahigh Cycling Stability
作者： Xuanpeng Wang , Chaojiang Niu , Jiashen Meng , Ping Hu , Xiaoming Xu
关键词:
摘要: Sodium-ion battery has captured much attention due to the abundant sodium resources and potentially low cost. However, it suffers from poor cycling stability diffusion coefficient, which seriously limit its widespread application. Here, K3V2(PO4)3/C bundled nanowires are fabricated usinga facile organic acid-assisted method. With a highly stable framework, nanoporous structure, conductive carbon coating, manifest excellent electrochemical performances in sodium-ion battery. A capacity of 119 mAh g−1 can be achieved at 100 mA g−1. Even high current density 2000 g−1, 96.0% retained after charge–discharge cycles. Comparing with blocks, show significantly improved stability. This work provides effective approach enhance performance batteries.
sci-hub.se 参考文章(47)
Min Woo Song, Min Kang, Kyung Lim Kim, Selective oxidation of hydrogen sulfide over potassium promoted vanadium oxide on a alumina catalysts Reaction Kinetics and Catalysis Letters. ,vol. 78, pp. 365- 371 ,(2003) , 10.1023/A:1022650314507
C.M Julien, M Massot, C Poinsignon, Lattice vibrations of manganese oxides. Part I. Periodic structures. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 60, pp. 689- 700 ,(2004) , 10.1016/S1386-1425(03)00279-8
Chaojiang Niu, Jiashen Meng, Xuanpeng Wang, Chunhua Han, Mengyu Yan, Kangning Zhao, Xiaoming Xu, Wenhao Ren, Yunlong Zhao, Lin Xu, Qingjie Zhang, Dongyuan Zhao, Liqiang Mai, General synthesis of complex nanotubes by gradient electrospinning and controlled pyrolysis Nature Communications. ,vol. 6, pp. 7402- 7402 ,(2015) , 10.1038/NCOMMS8402
H. Liu, F. C. Strobridge, O. J. Borkiewicz, K. M. Wiaderek, K. W. Chapman, P. J. Chupas, C. P. Grey, Capturing metastable structures during high-rate cycling of LiFePO4 nanoparticle electrodes Science. ,vol. 344, pp. 1252817- 1252817 ,(2014) , 10.1126/SCIENCE.1252817
Alar Jänes, Thomas Thomberg, Heisi Kurig, Enn Lust, Nanoscale fine-tuning of porosity of carbide-derived carbon prepared from molybdenum carbide Carbon. ,vol. 47, pp. 23- 29 ,(2009) , 10.1016/J.CARBON.2008.07.010
Peter Gölitz, Cover Picture: Champagne and Fireworks: Angewandte Chemie Celebrates Its Birthday (Angew. Chem. Int. Ed. 1/2013) Angewandte Chemie. ,vol. 52, pp. 1- 1 ,(2013) , 10.1002/ANIE.201209858
Zhenguo Yang, Jianlu Zhang, Michael C. W. Kintner-Meyer, Xiaochuan Lu, Daiwon Choi, John P. Lemmon, Jun Liu, Electrochemical Energy Storage for Green Grid Chemical Reviews. ,vol. 111, pp. 3577- 3613 ,(2011) , 10.1021/CR100290V
Vadivukarasi Raju, Jordan Rains, Cooper Gates, Wei Luo, Xingfeng Wang, William F. Stickle, Galen D. Stucky, Xiulei Ji, Superior cathode of sodium-ion batteries: orthorhombic V₂O₅ nanoparticles generated in nanoporous carbon by ambient hydrolysis deposition. Nano Letters. ,vol. 14, pp. 4119- 4124 ,(2014) , 10.1021/NL501692P
Geert Silversmit, Diederik Depla, Hilde Poelman, Guy B. Marin, Roger De Gryse, Determination of the V2p XPS binding energies for different vanadium oxidation states (V5+ to V0+) Journal of Electron Spectroscopy and Related Phenomena. ,vol. 135, pp. 167- 175 ,(2004) , 10.1016/J.ELSPEC.2004.03.004
Yang Liu, Yun Qiao, Wuxing Zhang, Henghui Xu, Zhen Li, Yue Shen, Lixia Yuan, Xianluo Hu, Xiang Dai, Yunhui Huang, High-performance aqueous sodium-ion batteries with K0.27MnO2 cathode and their sodium storage mechanism Nano Energy. ,vol. 5, pp. 97- 104 ,(2014) , 10.1016/J.NANOEN.2014.02.010