Solvation of electrons in various polar solvents: Can we predict the energy of the optical absorption maximum from the Kirkwood parameter?

作者: J.-P. Jay-Gerin , C. Ferradini

DOI: 10.1016/1359-0197(90)90012-7

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摘要: Abstract The Kirkwood parameter, g K , which indicates the degree of nonrandom structure in polar liquids, is calculated for 65 different pure solvents optical absorption spectrum excess thermal electrons has been reported literature. It shown that there no single-valued relationship between energy at maximum, E A max and .

参考文章(62)
N. R. Kestner, Colloque Weyl, Akademyah ha-leʾumit ha-Yiśreʾelit le-madaʿim, Joshua Jortner, Electrons in fluids : the nature of metal-ammonia solutions Springer. ,(1973)
J. BELLONI, J. FRADIM DE LA RENAUDIÈRE, Radiolytic Formation of Long-lived Ammoniated Electrons at Room Temperature Nature. ,vol. 232, pp. 173- 174 ,(1971) , 10.1038/PHYSCI232173A0
J. A. Delaire, M. O. Delcourt, J. Belloni, Mobilities of solvated electrons in polar solvents from scavenging rate constants The Journal of Physical Chemistry. ,vol. 84, pp. 1186- 1189 ,(1980) , 10.1021/J100447A024
Myran C. Sauer, Shigeyoshi Arai, Leon M. Dorfman, Pulse Radiolysis Studies. VII. The Absorption Spectra and Radiation Chemical Yields of the Solvated Electron in the Aliphatic Alcohols The Journal of Chemical Physics. ,vol. 42, pp. 708- 712 ,(1965) , 10.1063/1.1695994
Eric A. Shaede, Leon M. Dorfman, Garry J. Flynn, David C. Walker, Spectrum, Kinetics, and Radiation Chemical Yield of Solvated Electrons in Hexamethylphosphoric Triamide Canadian Journal of Chemistry. ,vol. 51, pp. 3905- 3913 ,(1973) , 10.1139/V73-582