Divalent metal phosphonates – new aspects for syntheses, in situ characterization and structure solution

摘要: Divalent metal phosphonates are promising hybrid materials with a broad field of application. The rich coordination chemistry the phosphonate linkers enables formation structures different dimensionalities ranging from isolated complexes and layered to porous frameworks incorporating various functionalities through choice building blocks. In brief, offer an interesting opportunity for design multifunctional materials. Here, we provide short review on class divalent discussing their syntheses, structures, applications. We present advantages recently introduced mechanochemical pathway Synthesis as possibility generate new, in certain cases metastable compounds. benefits situ investigation synthesis mechanisms well implementation sophisticated methods structure analysis resulting compounds discussed.