Quantifying Percolation Events in PEM Fuel Cell Using Synchrotron Radiography

作者: J. Hinebaugh , J. Lee , C. Mascarenhas , A. Bazylak

DOI: 10.1016/J.ELECTACTA.2015.09.058

关键词:

摘要: Abstract The distribution of independent water clusters within the gas diffusion layer (GDL) is an important, yet poorly understood, characteristic polymer electrolyte membrane fuel cells. A better understanding these would provide ex-situ invasion experiments and two-phase models with a set validation criteria that currently absent from literature. Synchrotron based X-ray radiography was employed visualize liquid emerging cell GDL. Droplet formations, entitled “breakthrough” events originated either channel or landing regions number breakthrough in given area (breakthrough density) provides insight into size evolving Water were found under flow field landings more frequently than channels. Each 1 mm 2 projected GDL to have 1-2 individual during most conditions studied, regardless substrate MPL type. existence percolating channels depended on combination type operating employed.

参考文章(42)
I. Manke, C. Hartnig, N. Kardjilov, H. Riesemeier, J. Goebbels, R. Kuhn, P. Krüger, J. Banhart, In situ Synchrotron X‐ray Radiography Investigations of Water Transport in PEM Fuel Cells Fuel Cells. ,vol. 10, pp. 26- 34 ,(2009) , 10.1002/FUCE.200800123
Reto Flückiger, Federica Marone, Marco Stampanoni, Alexander Wokaun, Felix N. Büchi, Investigation of liquid water in gas diffusion layers of polymer electrolyte fuel cells using X-ray tomographic microscopy Electrochimica Acta. ,vol. 56, pp. 2254- 2262 ,(2011) , 10.1016/J.ELECTACTA.2010.12.016
Jens Eller, Tomas Rosén, Federica Marone, Marco Stampanoni, Alexander Wokaun, Felix N. Büchi, Progress in In Situ X-Ray Tomographic Microscopy of Liquid Water in Gas Diffusion Layers of PEFC Journal of The Electrochemical Society. ,vol. 158, ,(2011) , 10.1149/1.3596556
J. Haußmann, H. Markötter, R. Alink, A. Bauder, K. Dittmann, I. Manke, J. Scholta, Synchrotron radiography and tomography of water transport in perforated gas diffusion media Journal of Power Sources. ,vol. 239, pp. 611- 622 ,(2013) , 10.1016/J.JPOWSOUR.2013.02.014
Zijie Lu, Michael M. Daino, Cody Rath, Satish G. Kandlikar, Water management studies in PEM fuel cells, part III: Dynamic breakthrough and intermittent drainage characteristics from GDLs with and without MPLs International Journal of Hydrogen Energy. ,vol. 35, pp. 4222- 4233 ,(2010) , 10.1016/J.IJHYDENE.2010.01.012
J BENZIGER, J NEHLSEN, D BLACKWELL, T BRENNAN, J ITESCU, Water flow in the gas diffusion layer of PEM fuel cells Journal of Membrane Science. ,vol. 261, pp. 98- 106 ,(2005) , 10.1016/J.MEMSCI.2005.03.049
Sang-Joon Lee, Seung-Gon Kim, Gu-Gon Park, Chang-Soo Kim, Quantitative visualization of temporal water evolution in an operating polymer electrolyte fuel cell International Journal of Hydrogen Energy. ,vol. 35, pp. 10457- 10463 ,(2010) , 10.1016/J.IJHYDENE.2010.07.173
Talal Ous, C. Arcoumanis, The formation of water droplets in an air-breathing PEMFC International Journal of Hydrogen Energy. ,vol. 34, pp. 3476- 3487 ,(2009) , 10.1016/J.IJHYDENE.2009.02.037
Jeff T. Gostick, Marios A. Ioannidis, Michael W. Fowler, Mark D. Pritzker, On the role of the microporous layer in PEMFC operation Electrochemistry Communications. ,vol. 11, pp. 576- 579 ,(2009) , 10.1016/J.ELECOM.2008.12.053