Vanadium catalyzed aerobic carbon–carbon cleavage
作者： Emanuele Amadio , Rosalia Di Lorenzo , Cristiano Zonta , Giulia Licini
DOI: 10.1016/J.CCR.2015.06.004
关键词:
摘要: Abstract In recent years, the use of vanadium complexes as catalysts and air or oxygen oxidants has emerged a new method for effective oxidative carbon–carbon bond cleavage in series substrates, including 1,2-diols α-hydroxy ethers. addition to advantageous synthetic tool, catalyzed aerobic C becomes even more appealing if applied degradation lignocellulosic biomass particular depolymerization/degradation lignin cellulose. this review, chemistry, most advances role played by homogeneous are presented discussed.
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