Photoinduced lnsertion of sulphur bridges into a CrSCr multiple bond, and X-ray crystal structure of (η5-C5H5)2Cr2(µ-S)2(µ-S2)

作者： Lai Yoong Goh , Thomas C. W. Mak

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摘要: Photoinduced insertion of sulphur ligands into the CrSCr multiple bond (η5-C5H5)2Cr2(CO)4S provides a novel route to new complex (η5-C5H5)2Cr2S4, which has one bidendate µ-S2 and two µ-S bridges symmetrically placed between (η5-C5H5)Cr moieties.

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Photoinduced lnsertion of sulphur bridges into a CrSCr multiple bond, and X-ray crystal structure of (η5-C5H5)2Cr2(µ-S)2(µ-S2)

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Photoinduced lnsertion of sulphur bridges into a CrSCr multiple bond, and X-ray crystal structure of (η5-C5H5)2Cr2(µ-S)2(µ-S2)

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