TiO2/carbon hollow spheres as anode materials for advanced sodium ion batteries

作者: Fuhua Yang , Zhian Zhang , Yu Han , Ke Du , Yanqing Lai

DOI: 10.1016/J.ELECTACTA.2015.08.051

关键词:

摘要: Abstract TiO2/carbon hollow spheres (TiO2/C-HSs) have been successfully prepared using a template method. During the synthesis procedures, SiO2 were used as template, titanium tert-butoxide and dopamine TiO2 carbon precursor, respectively. The TiO2/C-HSs characterized by X-ray diffraction (XRD), nitrogen adsorption-desorption measurements, scanning electron microscopy (SEM), transmission (TEM), thermogravimetry (TGA) raman spectra analysis. When utilized anode materials for sodium-ion batteries, can deliver high specific capacity remarkable rate performance. excellent electrochemical performance of be ascribed to sphere structure, existence large surface area porous structure.

参考文章(35)
Wei-Jie Li, Shu-Lei Chou, Jia-Zhao Wang, Hua-Kun Liu, Shi-Xue Dou, Simply mixed commercial red phosphorus and carbon nanotube composite with exceptionally reversible sodium-ion storage Nano Letters. ,vol. 13, pp. 5480- 5484 ,(2013) , 10.1021/NL403053V
Yan Zhang, Xuli Pu, Yingchang Yang, Yirong Zhu, Hongshuai Hou, Mingjun Jing, Xuming Yang, Jun Chen, Xiaobo Ji, None, An electrochemical investigation of rutile TiO2 microspheres anchored by nanoneedle clusters for sodium storage. Physical Chemistry Chemical Physics. ,vol. 17, pp. 15764- 15770 ,(2015) , 10.1039/C5CP01227A
J.-M. Tarascon, M. Armand, Issues and challenges facing rechargeable lithium batteries Nature. ,vol. 414, pp. 359- 367 ,(2001) , 10.1038/35104644
Ji Bong Joo, Qiao Zhang, Ilkeun Lee, Michael Dahl, Francisco Zaera, Yadong Yin, Mesoporous Anatase Titania Hollow Nanostructures though Silica-Protected Calcination Advanced Functional Materials. ,vol. 22, pp. 166- 174 ,(2012) , 10.1002/ADFM.201101927
Gang Liu, Hua Gui Yang, Jian Pan, Yong Qiang Yang, Gao Qing (Max) Lu, Hui-Ming Cheng, Titanium dioxide crystals with tailored facets Chemical Reviews. ,vol. 114, pp. 9559- 9612 ,(2014) , 10.1021/CR400621Z
Nian Liu, Hui Wu, Matthew T. McDowell, Yan Yao, Chongmin Wang, Yi Cui, A yolk-shell design for stabilized and scalable li-ion battery alloy anodes. Nano Letters. ,vol. 12, pp. 3315- 3321 ,(2012) , 10.1021/NL3014814
Yatim Lailun Ni'mah, Ming-Yao Cheng, Ju Hsiang Cheng, John Rick, Bing-Joe Hwang, Solid-state polymer nanocomposite electrolyte of TiO2/PEO/NaClO4 for sodium ion batteries Journal of Power Sources. ,vol. 278, pp. 375- 381 ,(2015) , 10.1016/J.JPOWSOUR.2014.11.047
Lin Wu, Xiaohong Hu, Jiangfeng Qian, Feng Pei, Fayuan Wu, Rongjun Mao, Xinping Ai, Hanxi Yang, Yuliang Cao, Sb–C nanofibers with long cycle life as an anode material for high-performance sodium-ion batteries Energy and Environmental Science. ,vol. 7, pp. 323- 328 ,(2014) , 10.1039/C3EE42944J
Yu-Guo Guo, Jin-Song Hu, Li-Jun Wan, Nanostructured Materials for Electrochemical Energy Conversion and Storage Devices Advanced Materials. ,vol. 20, pp. 2878- 2887 ,(2008) , 10.1002/ADMA.200800627
Verónica Palomares, Paula Serras, Irune Villaluenga, Karina B. Hueso, Javier Carretero-González, Teófilo Rojo, Na-ion batteries, recent advances and present challenges to become low cost energy storage systems Energy & Environmental Science. ,vol. 5, pp. 5884- 5901 ,(2012) , 10.1039/C2EE02781J