Water as Solvent in Organic Synthesis
作者： André Lubineau , Jacques Augé
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摘要: Organic reactions using water as solvent are reviewed with a focus on pericyclic reactions, carbonyl additions, stoichiometric organometallic oxidations and reductions which show an unusual outcome in terms of reactivity selectivity compared those performed organic solvent. The advantages discussed related to the hydrophobic effects hydrogen-bonding ability special emphasis its very high cohesive energy density strongly favors having negative activation volume.
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