One-step structure-directing approach to Ce3+-doped CaS luminescent micro-nanocrystals

作者: Zhongxian Qiu , Hongzhou Lian , Tingting Luo , Jian Fan , Xuechao Cai

DOI: 10.1039/C5CE01800E

关键词:

摘要: A one-step surfactant–ligand co-assisted solvothermal technique was proposed for the preparation of CaS-based luminescent materials with ethylenediamine as solvent, and acetylacetone, 1-dodecanethiol polyvinylpyrrolidone capping agents. The morphologies obtained particles can be adjusted from an octahedron to a hexagonal prism or cube by changing solvent volume ratios different agent(s), mean sizes crystals changed in relatively wide range tens nanometers few micrometers. growth process dynamic mechanism were discussed. series CaS:xCe3+ nanocrystals prepared small red shift emission positions observed green yellowish-green increasing Ce3+ concentration.

参考文章(41)
Shixun Lian, Zhongxian Qiu, Tingting Luo, Jilin Zhang, Wenli Zhou, Liping Yu, A green approach to green-conversion material and green-agriculture: alkaline-earth metal sulfide phosphors Journal of Materials Chemistry C. ,vol. 3, pp. 9631- 9636 ,(2015) , 10.1039/C5TC00694E
Ankush Vij, Surender Singh, Ravi Kumar, S P Lochab, V V S Kumar, Nafa Singh, Synthesis and luminescence studies of Ce doped SrS nanostructures Journal of Physics D. ,vol. 42, pp. 105103- ,(2009) , 10.1088/0022-3727/42/10/105103
Guogang Li, Chong Peng, Chunxia Li, Piaoping Yang, Zhiyao Hou, Yong Fan, Ziyong Cheng, Jun Lin, Shape-Controllable Synthesis and Morphology-Dependent Luminescence Properties of GaOOH:Dy3+ and β-Ga2O3:Dy3+ Inorganic Chemistry. ,vol. 49, pp. 1449- 1457 ,(2010) , 10.1021/IC901682X
Yiming Zhao, Freddy T. Rabouw, Tim van Puffelen, Cornelis A. van Walree, Daniel R. Gamelin, Celso de Mello Donegá, Andries Meijerink, Lanthanide-doped CaS and SrS luminescent nanocrystals : A single-source precursor approach for doping Journal of the American Chemical Society. ,vol. 136, pp. 16533- 16543 ,(2014) , 10.1021/JA5076663
Haoyang Zou, Ming Yan, Guanjun Wang, Bo Yuan, Jing Huang, Fei Gao, Ye Sheng, Keyan Zheng, Yanhua Song, Sr5(PO4)3Cl:Eu2 + with multiform morphologies and sizes: Hydrothermal synthesis and luminescent properties Powder Technology. ,vol. 254, pp. 579- 582 ,(2014) , 10.1016/J.POWTEC.2014.01.078
Shixun Lian, Chunying Rong, Dulin Yin, Shubin Liu, Enhancing Solar Energy Conversion Efficiency: A Tunable Dual-Excitation Dual-Emission Phosphors and Time-Dependent Density Functional Theory Study Journal of Physical Chemistry C. ,vol. 113, pp. 6298- 6302 ,(2009) , 10.1021/JP810877N
J. Gasiot, P. Bräunlich, J. P. Fillard, Nanosecond infrared laser stimulation of luminescence in rare‐earth doped sulfides Applied Physics Letters. ,vol. 40, pp. 376- 378 ,(1982) , 10.1063/1.93102
Chunxia Li, Jun Yang, Zewei Quan, Piaoping Yang, Deyan Kong, Jun Lin, Different Microstructures of β-NaYF4Fabricated by Hydrothermal Process:  Effects of pH Values and Fluoride Sources Chemistry of Materials. ,vol. 19, pp. 4933- 4942 ,(2007) , 10.1021/CM071668G
Vinay Kumar, Ravi Kumar, S P Lochab, Nafa Singh, Thermoluminescence studies of CaS : Bi nanocrystalline phosphors Journal of Physics D. ,vol. 39, pp. 5137- 5142 ,(2006) , 10.1088/0022-3727/39/24/007
Lothar Wondraczek, Miroslaw Batentschuk, Markus A Schmidt, Rudolf Borchardt, Simon Scheiner, Benjamin Seemann, Peter Schweizer, Christoph J Brabec, None, Solar spectral conversion for improving the photosynthetic activity in algae reactors Nature Communications. ,vol. 4, pp. 2047- 2047 ,(2013) , 10.1038/NCOMMS3047