DOI: 10.1080/01442350500037455
关键词:
摘要: Some of the recent developments in quantum dynamical studies at conical intersections molecular potential energy surfaces is briefly reviewed this article. Particular emphasis given to a variety processes studied by us past. The non-adiabatic effects due both electronic as well relativistic spin–orbit coupling are considered. discussions include Jahn–Teller effect (and also pseudo-Jahn–Teller whenever applicable) Rydberg emission spectrum triatomic hydrogen and photoelectron cyclopropane methyl fluoride, probing ClO2 reagent van der Waals Cl(2 P)+H2 reaction via photodetachment spectroscopy negative ions, ClO ClH , respectively, thermal scattering dynamics H+H2 reactions on multisheeted surfaces.