Quantum non-adiabatic dynamics through conical intersections: Spectroscopy to reactive scattering

作者: Susanta Mahapatra *

DOI: 10.1080/01442350500037455

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摘要: Some of the recent developments in quantum dynamical studies at conical intersections molecular potential energy surfaces is briefly reviewed this article. Particular emphasis given to a variety processes studied by us past. The non-adiabatic effects due both electronic as well relativistic spin–orbit coupling are considered. discussions include Jahn–Teller effect (and also pseudo-Jahn–Teller whenever applicable) Rydberg emission spectrum triatomic hydrogen and photoelectron cyclopropane methyl fluoride, probing ClO2 reagent van der Waals Cl(2 P)+H2 reaction via photodetachment spectroscopy negative ions, ClO ClH , respectively, thermal scattering dynamics H+H2 reactions on multisheeted surfaces.

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