UNIFIED TREATMENT OF LUMINESCENCE QUENCHING KINETICS IN MICELLES WITH QUENCHER MIGRATION ON THE BASIS OF A GENERALIZED SMOLUCHOWSKI APPROACH

摘要: The problem of luminescence quenching in micelles assisted by quencher interphase migration is addressed using a Smoluchowski approach without invoking any assumption neither on the statistical distribution quenchers among nor independence and processes. obtained decay function coincides to good degree accuracy with prediction originally developed stochastic model quenching. This illustrates applicability type general reaction kinetics microdisperse systems, such as micelles, reveals several tacit assumptions original model. effect micelle size polydispersity also discussed.