Gas chromatographic analysis of organophosphorus pesticides of horticultural concern

作者: Ana Agüera , Mariano Contreras , Amadeo R. Fernandez-Alba

DOI: 10.1016/0021-9673(93)83235-K

关键词:

摘要: Abstract An optimized GC method for the determination of 25 organophosphorus pesticides (OPs) currently applied to horticultural crops was developed. Four additional compounds were evaluated their suitability as internal standards. The linearity, reproducibility and recoveries are discussed. reliability routine analysis fruit vegetable samples is demonstrated. Registration analytical results a control sample in quality charts demonstrated performance this method. limits detection range 5–20 μg/kg. throughput ca. 68 per 24 h. Results also presented extracts four real fortified with target OPs. confirmed by GC-MS.

参考文章(17)
B. Griepink, Certified reference materials (CRM's) for the quality of measurement Fresenius Journal of Analytical Chemistry. ,vol. 337, pp. 812- 816 ,(1990) , 10.1007/BF00322257
S.M. Staroverov, A.A. Serdan, G.V. Lisichkin, Structure of the bonded layer and selectivity of chemically modified stationary phases for chromatography Journal of Chromatography A. ,vol. 364, pp. 377- 388 ,(1986) , 10.1016/S0021-9673(00)96228-9
Pieter R. de Beer, Louis P. van Dyk, Susan M. Prinsloo, Awie J. Viljoen, Laurraine H. Lotter, Inter-laboratory calibration for the quality control of pesticide residue analyses (1984–85) Analyst. ,vol. 112, pp. 673- 678 ,(1987) , 10.1039/AN9871200673
John P. G. Wilkins, Alan R. C. Hill, Donald F. Lee, Organophosphorus sulphides, sulphoxides and sulphones. Part 2. Characterisation by gas chromatography-mass spectrometry Analyst. ,vol. 110, pp. 1045- 1051 ,(1985) , 10.1039/AN9851001045
Stanley N. Deming, Multiple-criteria optimization Journal of Chromatography A. ,vol. 550, pp. 15- 25 ,(1991) , 10.1016/S0021-9673(01)88527-7
Á. Ambrus, H.-P. Thier, APPLICATION OF MULTIRESIDUE PROCEDURES IN PESTICIDES RESIDUES ANALYSIS. Pure and Applied Chemistry. ,vol. 58, pp. 1035- 1062 ,(1986) , 10.1351/PAC198658071035
A. Valverde Garcia, E. Gonzalez Pradas, J. Martinez Vidal, A. Aguera Lopez, Simple and efficient multiresidue screening method for analysis of nine halogen-containing pesticides on peppers and cucumbers by GLC-ECD Journal of Agricultural and Food Chemistry. ,vol. 39, pp. 2188- 2191 ,(1991) , 10.1021/JF00012A018