The synthesis of higher alcohols using modified Cu/ZnO/Al2O3 catalysts
作者： J.C. Slaa , J.G. van Ommen , J.R.H. Ross
DOI: 10.1016/0920-5861(92)80125-7
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摘要: This paper gives a review of research work in the synthesis higher alcohols over catalysts based on Cu/ZnO/Al2O3, emphasizing three main topics: (i) effect selectivity addition several compounds to this catalyst, (ii) reaction conditions used, and (iii) network leading different products found. Although use alkali has been studied most extensively, other compounds, for example those containing manganese, also appear be promising additives. The process are rather critical may cause some practical difficulties industrial plants. An extended aldol condensation mechanism is proposed which can explain product distribution
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