Gas-Phase Metal Reactions.

摘要: Abstract : The use of new advanced solid rocket propellant constituents, such as, e.g., boron as HEDM and ammonium nitrate replacement for halogen-containing oxidants, requires knowledge their combustion characteristics. To this end experimental rate coefficient k measurements on individual important Al B species reactions were made in the 300-1800 K temperature range using a high- fast-flow reactor. Temperature dependent expressions k(T) = AT(super n)exp(-E/RT) are found between AlO CH4, O2; N2O: AlCl N2O, CO2, SO 2; BCl SO2; BO CO2. allow semi-empirical predictions further metal oxidation reactions, two theories have been developed utilized. These Semi-Empirical Configuration Interaction theory prediction E from one to another metals-Transition State Theory at temperature. Dual military-civilian applications work discussed. jg p. 1