Facile Method for Determination of Amine Speciation in CO2 Capture Solutions
作者： Naser S. Matin , Joseph E. Remias , James K. Neathery , Kunlei Liu
DOI: 10.1021/IE300230K
关键词:
摘要: A simple and quantitatively reliable method for determination of amine speciation is introduced. The employs three experimental methods that should be readily accessible. results CO2 loaded aqueous solutions 30 wt % monoethanolamine (MEA) are used demonstration the show promising agreement with more complicated spectroscopic reported in literature. measurements were done at ambient temperature atmospheric pressure, since theoretical calculations data from open literature revealed no considerable difference different temperatures. procedure based on acid base titration solution along total loading. quantitative species concentration example MEA other available methods, mainly NMR, particularly free amine, carbamate, protonated concentrations. Aspen ...
acs.org
sci-hub.se 参考文章(24)
Jana Poplsteinova Jakobsen, Jostein Krane, Hallvard F. Svendsen, Liquid-Phase Composition Determination in CO2−H2O−Alkanolamine Systems: An NMR Study Industrial & Engineering Chemistry Research. ,vol. 44, pp. 9894- 9903 ,(2005) , 10.1021/IE048813+
Vincent Souchon, Marco de Oliveira Aleixo, Olivier Delpoux, Corinne Sagnard, Pascal Mougin, Aurélie Wender, Ludovic Raynal, In situ determination of species distribution in alkanolamine- H2O - CO2 systems by Raman spectroscopy Energy Procedia. ,vol. 4, pp. 554- 561 ,(2011) , 10.1016/J.EGYPRO.2011.01.088
Wolfram Böttinger, Michael Maiwald, Hans Hasse, Online NMR spectroscopic study of species distribution in MEA-H2O-CO2 and DEA-H2O-CO2 Fluid Phase Equilibria. ,vol. 263, pp. 131- 143 ,(2008) , 10.1016/J.FLUID.2007.09.017
M.Z. Haji-Sulaiman, M.K. Aroua, Md Ilyas Pervez, Equilibrium concentration profiles of species in CO2—alkanolamine—water systems Gas Separation & Purification. ,vol. 10, pp. 13- 18 ,(1996) , 10.1016/0950-4214(95)00021-6
Chee-Yan Chan, Yong-Wah Eng, Kok-Soon Eu, Pitzer Single-Ion Activity Coefficients and pH for Aqueous Solutions of Potassium Hydrogen Phthalate in Mixtures with KCl and with NaCl at 298.15 K Journal of Chemical & Engineering Data. ,vol. 40, pp. 685- 691 ,(1995) , 10.1021/JE00019A034
Abass A. Olajire, CO2 capture and separation technologies for end-of-pipe applications – A review Energy. ,vol. 35, pp. 2610- 2628 ,(2010) , 10.1016/J.ENERGY.2010.02.030
Jana P. Jakobsen, Eirik F. da Silva, Jostein Krane, Hallvard F. Svendsen, NMR study and quantum mechanical calculations on the 2-[(2-aminoethyl)amino]-ethanol-H2O-CO2 system. Journal of Magnetic Resonance. ,vol. 191, pp. 304- 314 ,(2008) , 10.1016/J.JMR.2007.12.022
Ross Dugas, Gary Rochelle, Absorption and desorption rates of carbon dioxide with monoethanolamine and piperazine Energy Procedia. ,vol. 1, pp. 1163- 1169 ,(2009) , 10.1016/J.EGYPRO.2009.01.153
Ying Zhang, Huiling Que, Chau-Chyun Chen, Thermodynamic modeling for CO2 absorption in aqueous MEA solution with electrolyte NRTL model Fluid Phase Equilibria. ,vol. 311, pp. 67- 75 ,(2011) , 10.1016/J.FLUID.2011.08.025
Catherine Goyet, Amy K. Snover, High-accuracy measurements of total dissolved inorganic carbon in the ocean: comparison of alternate detection methods Marine Chemistry. ,vol. 44, pp. 235- 242 ,(1993) , 10.1016/0304-4203(93)90205-3