Fabrication, Characterization, and Optoelectronic Properties of Layer-by-Layer Films Based on Terpyridine-Modified MWCNTs and Ruthenium(III) Ions
作者： Yuexiu Pan , Bin Tong , Jianbing Shi , Wei Zhao , Jinbo Shen
DOI: 10.1021/JP909904T
关键词:
摘要: A novel full-conjugated 4-(2,2′:6′,2′′-terpyrid-4′-yl) benzenediazonium tetrafluoroborate (diazo-tpy) was synthesized and used for surface modification of materials, such as quartz wafers, ITO glass, silicon, multiwalled carbon nanotubes (MWCNTs). Under UV irradiation, the diazonium group diazo-tpy is decomposed residual terpyridine covalently anchored to substrates. The obtained tpy-modified MWCNTs (tpy-MWCNTs) have good solubility in common organic solvents. TGA HRTEM analyses confirmed that groups been symmetrically grafted on MWCNTs. thickness monolayer about 2.3 nm, which approximately 2 times axial length 4-(2,2′:6′,2′′-terpyrid-4′-yl)phenyl group. introduction provides a coordination site complex with metal ions. Multilayer films were fabricated from tpy-MWCNTs ruthenium ions [Ru(III)] via layer-by-layer self-assembled (LBL SA) technique ...
acs.org
sci-hub.se 参考文章(110)
Sander J. Tans, Alwin R. M. Verschueren, Cees Dekker, Room-temperature transistor based on a single carbon nanotube Nature. ,vol. 393, pp. 49- 52 ,(1998) , 10.1038/29954
Michael Holzinger, Otto Vostrowsky, Andreas Hirsch, Frank Hennrich, Manfred Kappes, Robert Weiss, Frank Jellen, Sidewall Functionalization of Carbon Nanotubes This work was supported by the European Union under the 5th Framework Research Training Network 1999, HPRNT 1999-00011 FUNCARS. Angewandte Chemie. ,vol. 40, pp. 4002- 4005 ,(2001) , 10.1002/1521-3773(20011105)40:21<4002::AID-ANIE4002>3.0.CO;2-8
Nikos Tagmatarchis, Vasilios Georgakilas, Maurizio Prato, Hisanori Shinohara, Sidewall functionalization of single-walled carbon nanotubes through electrophilic additionElectronic supplementary information (ESI) available: Fig. S1: TEM views of functionalized nanotubes 1. Fig. S2: 1H NMR spectrum of functionalized SWNTs 2 material. See http://www.rsc.org/suppdata/cc/b2/b204366a/ Chemical Communications. pp. 2010- 2011 ,(2002) , 10.1039/B204366A
Yves Bodenthin, Ullrich Pietsch, Helmuth Möhwald, Dirk G. Kurth, Inducing spin crossover in metallo-supramolecular polyelectrolytes through an amphiphilic phase transition. Journal of the American Chemical Society. ,vol. 127, pp. 3110- 3114 ,(2005) , 10.1021/JA0447210
Richard H. Fish, Kim. Tae-Jeong, Joanne L. Stewart, John H. Bushweller, Robert K. Rosen, Wisner Jean. Dupon, Synthesis of dimetallaazacyclobutenes via reaction of polynuclear heteroaromatic nitrogen compounds with triruthenium dodecacarbonyl: reactivity and structural elucidation Organometallics. ,vol. 5, pp. 2193- 2198 ,(1986) , 10.1021/OM00142A005
Jonathon E. Beves, Edwin C. Constable, Catherine E. Housecroft, Markus Neuburger, Silvia Schaffner, A pyrazolyl-terminated 2,2':6',2 -terpyridine ligand : Iron(II), ruthenium(II) and palladium(II) complexes of 4'-(3,5-dimethylpyrazol-1-yl)-2,2': 6',2 -terpyridine Polyhedron. ,vol. 27, pp. 2395- 2401 ,(2008) , 10.1016/J.POLY.2008.04.022
Yue Liu, Yongxiang Wang, Jianyu Jin, Hao Wang, Ronghua Yang, Weihong Tan, Fluorescent assay of DNA hybridization with label-free molecular switch: reducing background-signal and improving specificity by using carbon nanotubes Chemical Communications. pp. 665- 667 ,(2009) , 10.1039/B819526A
Tadaaki Ikoma, Hiroki Oshio, Masashi Yamamoto, Yasunori Ohba, Masayuki Nihei, Peculiarity in the Electronic Structure of Cu(II) Complex Ferromagnetically Coupled with Bisimino Nitroxides Journal of Physical Chemistry A. ,vol. 112, pp. 8641- 8648 ,(2008) , 10.1021/JP802810S
Dirk G. Kurth, Annette Meister, Andreas F. Thünemann, Günter Förster, Structure of a liquid crystalline metallosupramolecular polyelectrolyte-amphiphile complex at the nanoscopic level Langmuir. ,vol. 19, pp. 4055- 4057 ,(2003) , 10.1021/LA026757G
Marc Altman, Atindra D Shukla, Tatiana Zubkov, Guennadi Evmenenko, Pulak Dutta, Milko E Van Der Boom, None, Controlling structure from the bottom-up: structural and optical properties of layer-by-layer assembled palladium coordination-based multilayers. Journal of the American Chemical Society. ,vol. 128, pp. 7374- 7382 ,(2006) , 10.1021/JA061026E