Laser induced photolysis of ozone in the visible: A kinetic study of O(3P) by atomic absorption spectroscopy
作者： I. Arnold , F.J. Conies
DOI: 10.1016/0022-2860(80)85139-8
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摘要: Abstract Time-resolved atomic resonance absorption spectroscopy has been used to study the reactions of ground state oxygen atoms, O(3P), formed in photodissociation ozone at 600 nm. A critical evaluation experimental procedure is made and problems arising from mismatch line profiles are discussed. The resulting temperature dependence rate constant O—O2 recombination reaction with N2 as third collision partner significantly different that reported earlier affects atmospheric model calculations.
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sci-hub.se 参考文章(7)
L.F. Phillips, Theoretical curves of growth for O(1D) absorption at 115.2 nm Chemical Physics Letters. ,vol. 37, pp. 421- 424 ,(1976) , 10.1016/0009-2614(76)85005-1
I. Arnold, F.J. Comes, Temperature dependence of the reactions O(3P) + O3 → 2O2 and O(3P) + O2 + M → O3 + M Chemical Physics. ,vol. 42, pp. 231- 239 ,(1979) , 10.1016/0301-0104(79)85182-4
Assa Lifshitz, Gordon B. Skinner, David R. Wood, Resonance absorption measurements of atom concentrations in reacting gas mixtures. I. Shapes of H and D Lyman‐α lines from microwave sources Journal of Chemical Physics. ,vol. 70, pp. 5607- 5613 ,(1979) , 10.1063/1.437437
R. F. Heidner, D. Husain, A study of the collisional quenching of O(21D2) by the noble gases employing time-resolved attenuation of atomic resonance radiation in the vacuum ultraviolet International Journal of Chemical Kinetics. ,vol. 6, pp. 77- 87 ,(1974) , 10.1002/KIN.550060108
Laser Induced Processes in Molecules Europhysics News. ,vol. 10, pp. 10- ,(1979) , 10.1007/978-3-642-67254-5
Peter P. Bemand, Michael A. A. Clyne, Atomic resonance fluorescence spectrometry for rate constants of rapid bimolecular reactions. Part 3.—Oxygen atom resonance O 3S1–3P2, 1, 0 Journal of the Chemical Society, Faraday Transactions. ,vol. 69, pp. 1643- 1658 ,(1973) , 10.1039/F29736901643
Robert E. Huie, John T. Herron, Douglas D. Davis, Absolute rate constants for the reaction O + O2 + M .far. O3 + M over the temperature range 200-346.deg.K The Journal of Physical Chemistry. ,vol. 76, pp. 2653- 2658 ,(1972) , 10.1021/J100663A002