Mantle-derived carbon in Hercynian granites. Stable isotopes signatures and C/He associations in the thermomineral waters, N-Portugal

作者: Paula M. Carreira , José M. Marques , M. Rosário Carvalho , Giorgio Capasso , Fausto Grassa

DOI: 10.1016/J.JVOLGEORES.2009.10.008

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摘要: article i nfo Na-HCO3-CO2-rich thermomineral waters issue in the N of Portugal, within Galicia-Tras-os-Montes region, linked to a major NNE-trending fault, so-called Penacova-Regua-Verin megalineament. Along this tectonic structure different occurrences CO2-rich are found: Chaves hot (67 °C) and also several cold (16.1 waters. The δ 2 H 18 O values similar those local meteoric chemical composition both mineral suggests that water-rock reactions mainly controlled by amount dissolved CO2 (g) rather than water temperature. Stable carbon isotope data indicate an external inorganic origin for gas. 13 CCO2 ranging between −7.2‰ −5.1‰ consistent with two-component

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