Near-infrared intraconfigurational luminescence spectroscopy of the Mn5+ (3d2) ion in Ca2PO4Cl, Sr5(PO4)3Cl, Ca2VO4Cl and Sr2VO4Cl
作者： J.A. Capobianco , G. Cormier , M. Bettinelli , R. Moncorgé , H. Manaa
DOI: 10.1016/0022-2313(92)90043-9
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摘要: Abstract Details of the fluorescence and vibrational properties MnO3-4 doped in Ca2PO4Cl, Sr5(PO4)3Cl, Ca2VO4Cl Sr2VO4Cl crystals were studied using laser spectroscopy. The dynamics different hosts is analysed detail. structure bands assignments are proposed. We report on appearance a progression non-totally symmetric mode v2(e) which indicative dynamic Jahn-Teller effect. have deduced characteristic lattice modes from Raman scattering emission
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