Defect types and defect properties in FeAl alloys

作者: J. Wolff , M. Franz , A. Broska , B. Köhler , Th. Hehenkamp

DOI: 10.1016/S0921-5093(97)00584-4

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摘要: Abstract The thermomechanical behavior of high temperature intermetallic alloys is related to point defects and their concentration. Positron annihilation a sensitive tool obtain various information about defect properties. In the FeAl system formation enthalpy decreases from 1.6 2.0 eV in pure α -Fe 1.37 (Fe–7at.%Al) 0.91eV D0 3 structure. Additionally, volume increases 0.88 Ω Fe–7at.%Al 1.42 Fe–40at.%Al (Ω=mean atomic volume). change indicates different types defects. quenching experiments migration measured using fast Doppler broadening technique changes 0.5 1.2 eV. Furthermore, knowledge positron lifetimes gives an additional hint main positions lattice. results suggest that thermal B2 phase are mainly triple at low double vacancies higher temperatures. A2 as well structure single supposed be predominant types.

参考文章(35)
D. Segers, M. Dorikens, L. Dorikens-Vanpraet, Positron annihilation : ICPA-8, Gent, Belgium, 29 August-3 September 1988 World Scientific. ,(1989)
V. M. Fal'chenko, V. V. Geichenko, Leonid Nikandrovich Larikov, Diffusion processes in ordered alloys Oxonian Press. ,(1981)
Ortrud Kubaschewski, Iron-binary phase diagrams ,(1982)
Positrons in solids Positrons in Solids. Series: Topics in Current Physics. ,vol. 12, ,(1979) , 10.1007/978-3-642-81316-0
H.-E. Schaefer, R. Würschum, M. Sǒb, T. Zák, W. Z. Yu, W. Eckert, F. Banhart, Thermal vacancies and positron-lifetime measurements in Fe 76.3 Al 23.7 Physical Review B. ,vol. 41, pp. 11869- 11874 ,(1990) , 10.1103/PHYSREVB.41.11869
Joachim Wolff, Matthias Franz, Theodor Hehenkamp, Defect analysis with positron annihilation — Applications to Fe aluminides Mikrochimica Acta. ,vol. 125, pp. 263- 268 ,(1997) , 10.1007/BF01246194
R. Würschum, C. Grupp, H.-E. Schaefer, Simultaneous study of vacancy formation and migration at high temperatures in B2-type Fe aluminides. Physical Review Letters. ,vol. 75, pp. 97- 100 ,(1995) , 10.1103/PHYSREVLETT.75.97
Helmut Mehrer, Diffusion in Intermetallics Materials Transactions Jim. ,vol. 37, pp. 1259- 1280 ,(1996) , 10.2320/MATERTRANS1989.37.1259