Effect of TiO2-ZnO/GAC on by-product distribution of CVOCs decomposition in a NTP-assisted catalysis system

作者: Kamaladdin Abedi , Farshid Ghorbani-Shahna , Abdolrahman Bahrami , Babak Jaleh , Rasoul Yarahmadi

DOI: 10.1515/PJCT-2015-0006

关键词:

摘要: In this study, the catalytic effect of TiO2-ZnO/GAC coupled with non-thermal plasma was investigated on byproducts distribution decomposition chlorinated VOCs in gas streams. The specifi c input energy, and initial composition examined a corona discharge reactor energized by high frequency pulsed power supply. Detected by-products for NTP at 750 J L –1 included CO, CO2, Cl2, trichloroacetaldehyde, as well trichlorobenzaldehyde chloroform feeding, while they were dominated lower abundance Cl2 chlorobenzene introduction. Some such O3, NO, NO2, COCl2 disappeared totally over TiO2-ZnO/GAC. Furthermore, amount heavy products decreased signifi cantly favor small molecules hybrid process. selectivity towards COx soared up to 77% catalyst 100 ppm

参考文章(47)
K.-P. Francke, H. Miessner, R. Rudolph, Cleaning of Air Streams from Organic Pollutants by Plasma-Catalytic Oxidation Plasma Chemistry and Plasma Processing. ,vol. 20, pp. 393- 403 ,(2000) , 10.1023/A:1007048428975
Chunwei Yuan, Yan Hu, Low-temperature Preparation of Photocatalytic TiO2 Thin Films on Polymer Substrates by Direct Deposition from Anatase Sol Journal of Materials Science & Technology. ,vol. 22, pp. 239- 244 ,(2009)
Jinhan Mo, Yinping Zhang, Qiujian Xu, Jennifer Joaquin Lamson, Rongyi Zhao, Photocatalytic purification of volatile organic compounds in indoor air: A literature review Atmospheric Environment. ,vol. 43, pp. 2229- 2246 ,(2009) , 10.1016/J.ATMOSENV.2009.01.034
J. Karuppiah, E. Linga Reddy, P. Manoj Kumar Reddy, B. Ramaraju, Ch. Subrahmanyam, Catalytic nonthermal plasma reactor for the abatement of low concentrations of benzene International Journal of Environmental Science and Technology. ,vol. 11, pp. 311- 318 ,(2014) , 10.1007/S13762-013-0218-Z
Shinsuke Iijima, Morito Nakamura, Akira Yokoi, Mitsuhiro Kubota, Liwei Huang, Hitoki Matsuda, Decomposition of dichloromethane and in situ alkali absorption of resulting halogenated products by a packed-bed non-thermal plasma reactor Journal of Material Cycles and Waste Management. ,vol. 13, pp. 206- 212 ,(2011) , 10.1007/S10163-011-0022-0
Jim Van Durme, Jo Dewulf, Christophe Leys, Herman Van Langenhove, Combining non-thermal plasma with heterogeneous catalysis in waste gas treatment: A review Applied Catalysis B-environmental. ,vol. 78, pp. 324- 333 ,(2008) , 10.1016/J.APCATB.2007.09.035
Martyn V. Twigg, Rôles of catalytic oxidation in control of vehicle exhaust emissions Catalysis Today. ,vol. 117, pp. 407- 418 ,(2006) , 10.1016/J.CATTOD.2006.06.044
H.R. Snyder, G.K. Anderson, Effect of air and oxygen content on the dielectric barrier discharge decomposition of chlorobenzene IEEE Transactions on Plasma Science. ,vol. 26, pp. 1695- 1699 ,(1998) , 10.1109/27.747888
Chan-Soon Kang, Young-Jae You, Ki-Joong Kim, Tae-hee Kim, Seong-Jun Ahn, Kyong-Hwan Chung, Nam-Cook Park, Shoichi Kimura, Ho-Geun Ahn, Selective catalytic reduction of NOx with propene over double wash-coat monolith catalysts Catalysis Today. ,vol. 111, pp. 229- 235 ,(2006) , 10.1016/J.CATTOD.2005.10.031