Thermal degradation study of fire resistive coating containing melamine polyphosphate and dipentaerythritol

作者: Guojian Wang , Jiayun Yang

DOI: 10.1016/J.PORGCOAT.2011.07.001

关键词:

摘要: Abstract A melamine polyphosphate (MPP)/dipentaerythritol (DPER) mixture was used as fire retardant additives for preparing waterborne intumescent resistive coating. The thermal degradation of the MPP/DPER and coating studied by TGA FTIR. resulting char investigated XPS, SEM energy dispersive spectroscopy (EDS). results showed that behavior similar to They decomposed nonflammable gases, formed layer containing phosphorus oxide at high temperature. EDS proved gradually oxidized with temperature increase. micrographs average cell size layers became bigger distribution wider increased from 500 °C 800 °C, this non-uniform could damage protection

参考文章(33)
Daming Feng, Zhengmao Zhou, Meiping Bo, An investigation of the thermal degradation of melamine phosphonite by XPS and thermal analysis techniques Polymer Degradation and Stability. ,vol. 50, pp. 65- 70 ,(1995) , 10.1016/0141-3910(95)00123-4
H. Abd El-Wahab, M. Abd El-Fattah, M.Y. Gabr, Preparation and characterization of flame retardant solvent base and emulsion paints Progress in Organic Coatings. ,vol. 69, pp. 272- 277 ,(2010) , 10.1016/J.PORGCOAT.2010.06.005
Lijuan Chen, Lei Song, Pin Lv, Ganxin Jie, Qilong Tai, Weiyi Xing, Yuan Hu, A new intumescent flame retardant containing phosphorus and nitrogen: Preparation, thermal properties and application to UV curable coating Progress in Organic Coatings. ,vol. 70, pp. 59- 66 ,(2011) , 10.1016/J.PORGCOAT.2010.10.002
Zhidong Han, Alberto Fina, Giulio Malucelli, Giovanni Camino, Testing fire protective properties of intumescent coatings by in-line temperature measurements on a cone calorimeter Progress in Organic Coatings. ,vol. 69, pp. 475- 480 ,(2010) , 10.1016/J.PORGCOAT.2010.09.001
Weigang Xu, Hongtao Zhang, Zhenming Yang, Jinsong Zhang, The effective thermal conductivity of three-dimensional reticulated foam materials Journal of Porous Materials. ,vol. 16, pp. 65- 71 ,(2009) , 10.1007/S10934-007-9169-4
J. A. Rhys, Intumescent coatings and their uses Fire and Materials. ,vol. 4, pp. 154- 156 ,(1980) , 10.1002/FAM.810040308
Şeref Kurt, Burhanettin Uysal, Cemal Özcan, Thermal conductivity of oriental beech impregnated with fire retardant Journal of Coatings Technology and Research. ,vol. 6, pp. 523- 530 ,(2009) , 10.1007/S11998-008-9158-9