Role of temperature and oxygen content on structural and electrical properties of LaBaCo2O5+δ thin films.

作者: Brennan Mace , Zach Harrell , Chonglin Chen , Erik Enriquez , Aiping Chen

DOI: 10.1063/1.5009245

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摘要: The role of temperature and the oxygen content in structural transformation electrical conductivity epitaxial double perovskite LaBaCo2O5+δ (0≤ δ ≤ 1) thin films was systematically investigated. Reciprocal space mapping ω-2θ x-ray diffraction performed at different temperatures vacuum indicate that vacancies become ordered high a reducing environment. changes degree vacancy ordering result strong in-plane anisotropic lattice deformation large thermal expansion coefficient along c-axis direction. measurements reveal these behaviors are related to formation films.

参考文章(39)
Wolfgang Donner, Chonglin Chen, Ming Liu, Allan J. Jacobson, Yueh-Lin Lee, Milind Gadre, Dane Morgan, Epitaxial Strain-Induced Chemical Ordering in La0.5Sr0.5CoO3−δ Films on SrTiO3 Chemistry of Materials. ,vol. 23, pp. 984- 988 ,(2011) , 10.1021/CM102657V
A.Yu. Suntsov, I.A. Leonidov, M.V. Patrakeev, V.L. Kozhevnikov, High-temperature electron–hole transport in PrBaCo2O5+δ Journal of Solid State Chemistry. ,vol. 184, pp. 1951- 1955 ,(2011) , 10.1016/J.JSSC.2011.05.045
Dashan Wang, James J. Tunney, Xiaomei Du, Michael L. Post, Raynald Gauvin, Thermal stability of SrFeO3/Al2O3 thin films: Transmission electron microscopy study and conductometric sensing response Journal of Applied Physics. ,vol. 104, pp. 023530- ,(2008) , 10.1063/1.2957073
J.-H. Kim, A. Manthiram, LnBaCo2O5+δ oxides as cathodes for intermediate-temperature solid oxide fuel cells Journal of The Electrochemical Society. ,vol. 155, ,(2008) , 10.1149/1.2839028
Yuri Diaz-Fernandez, Lorenzo Malavasi, Maria Cristina Mozzati, Effect of oxygen content on properties of theHoBaCo2O5+δlayered cobaltite Physical Review B. ,vol. 78, pp. 144405- ,(2008) , 10.1103/PHYSREVB.78.144405
Diana Garcés, Cristian F. Setevich, Alberto Caneiro, Gabriel Julio Cuello, Liliana Mogni, Effect of cationic order–disorder on the transport properties of LaBaCo2O6–δ and La0.5Ba0.5CoO3–δ perovskites Journal of Applied Crystallography. ,vol. 47, pp. 325- 334 ,(2014) , 10.1107/S1600576713031233
Jian Liu, Gregory Collins, Ming Liu, CL Chen, Jiechao Jiang, Efsftathios I Meletis, Qingyu Zhang, Chuang Dong, None, PO2 dependant resistance switch effect in highly epitaxial (LaBa)Co2O5+δ thin films Applied Physics Letters. ,vol. 97, pp. 094101- ,(2010) , 10.1063/1.3484964
A. Bartasyte, V. Plausinaitiene, A. Abrutis, T. Murauskas, P. Boulet, S. Margueron, J. Gleize, S. Robert, V. Kubilius, Z. Saltyte, Residual stresses and clamped thermal expansion in LiNbO3 and LiTaO3 thin films Applied Physics Letters. ,vol. 101, pp. 122902- ,(2012) , 10.1063/1.4752448
S.L. Pang, X.N. Jiang, X.N. Li, Q. Wang, Q.Y. Zhang, Structural stability and high-temperature electrical properties of cation-ordered/disordered perovskite LaBaCoO Materials Chemistry and Physics. ,vol. 131, pp. 642- 646 ,(2012) , 10.1016/J.MATCHEMPHYS.2011.10.029