Synthesis of New Main Group Ring and Cage Compounds

作者: T. Chen , E. N. Duesler , R. T. Paine , H. Nöth

DOI: 10.1080/10426509408021800

关键词:

摘要: Abstract The reactions of 1-(lithio·DME) salts two 1,3,2,4-diphosphadiboretanes with R2ECl2 reagents have been examined. Under most conditions, this chemistry provides precursors to novel cage compounds P2(BNR′2)2ER2, although in some cases soluble oligomers are formed when the intermediate species undergo dehydrohalogenation.

参考文章(29)
Ionel Haiduc, D. B. Sowerby, The chemistry of inorganic homo- and heterocycles ,(1970)
Peter Kölle, Gerard Linti, Heinrich Nöth, Kurt Polborn, Beiträge zur Chemie des Bors: CXCVII. Synthese, Struktur und Komplexbildung von 1,3,2,4-Diphosphadiborabicyclo[1.1.0]butanen☆☆☆ Journal of Organometallic Chemistry. ,vol. 355, pp. 7- 18 ,(1988) , 10.1016/0022-328X(88)89006-5
Danan Dou, Bernhard Kaufmann, Eileen N. Duesler, Tuqiang Chen, Robert T. Paine, H. Noeth, Synthesis and structures of main group cage compounds containing boron, silicon, and phosphorus atoms Inorganic Chemistry. ,vol. 32, pp. 3056- 3067 ,(1993) , 10.1021/IC00066A016
Danan Dou, Eileen N. Duesler, Robert T. Paine, Heinrich Noeth, Formation of a novel [cyclic] P-B-N-C ring via an intramolecular carbon-hydrogen activation process Journal of the American Chemical Society. ,vol. 114, pp. 9691- 9692 ,(1992) , 10.1021/JA00050A077
Peter Kölle, Heinrich Nöth, Robert T. Paine, Beiträge zur Chemie des Bors, 196. Darstellung und Reaktionen eines 3‐Amino‐1,2,3‐azaphosphaboriridins Chemische Berichte. ,vol. 122, pp. 423- 426 ,(1989) , 10.1002/CBER.19891220305
Ruth A. Bartlett, H. V. Rasika Dias, Xudong Feng, Philip P. Power, Synthesis and spectroscopic and x-ray structural characterization of compounds involving boron-phosphorus multiple bonds. Lithium salts of boryl phosphides and their precursors Journal of the American Chemical Society. ,vol. 111, pp. 1306- 1311 ,(1989) , 10.1021/JA00186A023
Philip P. Power, Boron‐Phosphorus Compounds and Multiple Bonding Angewandte Chemie. ,vol. 29, pp. 449- 460 ,(1990) , 10.1002/ANIE.199004491
R. T. Paine, D. Dou, M. Westerhausen, E. N. Duesler, G. Linti, H. Nöth, Synthesis and Reactivity of Borylphosphanes Phosphorus Sulfur and Silicon and The Related Elements. ,vol. 77, pp. 61- 64 ,(1993) , 10.1080/10426509308045619