Laser induced non-linear thermochemical processes in polymers

作者: L. I. Kalontarov , R. Marupov

DOI: 10.1007/BF01130114

关键词:

摘要: Laser induced thermochemical processes in the thin films of polyvinyl alcohol (PVA) and polyacrylnitrile (PAN) had been studied. It was found that laser thermodehydration PVA three stages: activation stage, stage instability stationary one. Such process dynamics can be explained by alteration positive negative feedback between thermal chemical degrees freedom. There shown, theoretically experimentally, possibility spontaneous formation spatially-inhomogeneous structures during dehydration due to inhomogeneity heating. also non-linear reactions influence stability PAN leading an unexpected dependence last one on polymeric film thickness.

参考文章(4)
Jesse Kramer, John Ross, Thermochemical bistability in an illuminated liquid-phase reaction The Journal of Physical Chemistry. ,vol. 90, pp. 923- 926 ,(1986) , 10.1021/J100277A043
E. C. Zimmermann, Mark Schell, John Ross, Stabilization of unstable states and oscillatory phenomena in an illuminated thermochemical system: Theory and experiment The Journal of Chemical Physics. ,vol. 81, pp. 1327- 1336 ,(1984) , 10.1063/1.447764
E. C. Zimmermann, John Ross, Light induced bistability in S2O6F2⇄2 SO3F: Theory and experiment Journal of Chemical Physics. ,vol. 80, pp. 720- 729 ,(1984) , 10.1063/1.446778
Jesse Kramer, Johannes Reiter, John Ross, Propagation of a chemical pulse in an illuminated thermochemical bistable system The Journal of Chemical Physics. ,vol. 84, pp. 1492- 1499 ,(1986) , 10.1063/1.450495