摘要: A new adsorption equation,viz.,\(a = \frac{{\rm A}}{{1 + \alpha \cdot e^{ - k^c } }}\) has been derived for those cases of where the previously adsorbed molecules facilitate more striking surface adsorbent. This equation fits in well with data yielding familiar S-shaped curves and should find extensive application.
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Stephen Brunauer, P. H. Emmett, Edward Teller, Adsorption of Gases in Multimolecular Layers Journal of the American Chemical Society. ,vol. 60, pp. 309- 319 ,(1938) , 10.1021/JA01269A023
Measurements of adsorption at the air-water interface by the microtome method Proceedings of The Royal Society A: Mathematical, Physical and Engineering Sciences. ,vol. 154, pp. 608- 623 ,(1936) , 10.1098/RSPA.1936.0072
S. J. Gregg, J. Jacobs, An examination of the adsorption theory of Brunauer, Emmett, and Teller, and Brunauer, Deming, Deming and Teller Transactions of The Faraday Society. ,vol. 44, pp. 574- 588 ,(1948) , 10.1039/TF9484400574
James W. McBain, George P. Davies, AN EXPERIMENTAL TEST OF THE GIBBS ADSORPTION THEOREM: A STUDY OF THE STRUCTURE OF THE SURFACE OF ORDINARY SOLUTIONS1 Journal of the American Chemical Society. ,vol. 49, pp. 2230- 2254 ,(1927) , 10.1021/JA01408A016
Albert Sprague Coolidge, THE ADSORPTION OF WATER VAPOR BY CHARCOAL Journal of the American Chemical Society. ,vol. 49, pp. 708- 721 ,(1927) , 10.1021/JA01402A014
Stephen Brunauer, Lola S. Deming, W. Edwards Deming, Edward Teller, On a Theory of the van der Waals Adsorption of Gases Journal of the American Chemical Society. ,vol. 62, pp. 1723- 1732 ,(1940) , 10.1021/JA01864A025
James W. McBain, J. L. Porter, R. F. Sessions, The Nature of the Sorption of Water by Charcoal Journal of the American Chemical Society. ,vol. 55, pp. 2294- 2304 ,(1933) , 10.1021/JA01333A014
James W. McBain, Robert DuBois, FURTHER EXPERIMENTAL TESTS OF THE GIBBS ADSORPTION THEOREM. THE STRUCTURE OF THE SURFACE OF ORDINARY SOLUTIONS Journal of the American Chemical Society. ,vol. 51, pp. 3534- 3549 ,(1929) , 10.1021/JA01387A005