Supported transition metal compounds ☆: Infrared studies on the acidity of Co/ZSM-5 and Fe/ZSM-5 catalysts
作者： Kee H. Rhee , V. Udaya , S. Rao , John M. Stencel , Gordon A. Melson
DOI: 10.1016/0144-2449(83)90179-3
关键词:
摘要: The acidity of Fe/ZSM-5 and Co/ZSM-5 synthesis gas conversion catalysts, prepared by extraction Fe3(CO)12 Co2(CO)8, is investigated infrared characterization chemisorbed pyridine. A portion the total concentration iron or cobalt shown to incorporate into channels ZSM-5. Such incorporation involves ion-exchange during Co2(CO)8 onto ZSM-5 but occurs only upon H2 reduction subsequent extraction. causes a redistribution Bronsted Lewis As result this redistribution, oxidation state ion-exchanged calculated.
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