Multicolor, large-area fluorescence sensing through oligothiophene-self-assembled monolayers.

作者: Manuela Melucci , Massimo Zambianchi , Laura Favaretto , Vincenzo Palermo , Emanuele Treossi

DOI: 10.1039/C0CC04478D

关键词:

摘要: We present a new strategy to realize self-assembled monolayers (SAMs) on quartz and silicon with multicolour fluorescence pattern starting from single, proton sensitive oligothiophene dye exposed at defined pH. Fine tuning of the SAMs emission color over entire visible range, including white, is demonstrated. Finally, integration in patterned thin layer cells (TLCs) exploited demonstrate cation sensing potential real devices.

参考文章(29)
Theresa Chang, Dorota I. Rozkiewicz, Bart Jan Ravoo, E. W. Meijer, David N. Reinhoudt, Directional movement of dendritic macromolecules on gradient surfaces. Nano Letters. ,vol. 7, pp. 978- 980 ,(2007) , 10.1021/NL070005V
Emanuele Treossi, Manuela Melucci, Andrea Liscio, Massimo Gazzano, Paolo Samorì, Vincenzo Palermo, High-Contrast Visualization of Graphene Oxide on Dye-Sensitized Glass, Quartz, and Silicon by Fluorescence Quenching Journal of the American Chemical Society. ,vol. 131, pp. 15576- 15577 ,(2009) , 10.1021/JA9055382
Christof Wöll, Interfacial Systems Chemistry: Towards the Remote Control of Surface Properties Angewandte Chemie. ,vol. 48, pp. 8406- 8408 ,(2009) , 10.1002/ANIE.200902974
Silvia V. Rocha, Nathaniel S. Finney, Synthesis and Evaluation of 2,5-Linked Alternating Pyridine−Thiophene Oligomers Organic Letters. ,vol. 12, pp. 2598- 2601 ,(2010) , 10.1021/OL1007907
Guy D. Joly, Lars Geiger, Steven E. Kooi, Timothy M. Swager, Highly Effective Water-Soluble Fluorescence Quenchers of Conjugated Polymer Thin Films in Aqueous Environments Macromolecules. ,vol. 39, pp. 7175- 7177 ,(2006) , 10.1021/MA061618H
Manuela Melucci, Massimo Zambianchi, Giovanna Barbarella, Ilse Manet, Marco Montalti, Sara Bonacchi, Enrico Rampazzo, Diana Cristina Rambaldi, Andrea Zattoni, Pierluigi Reschiglian, Facile tuning from blue to white emission in silica nanoparticles doped with oligothiophene fluorophores Journal of Materials Chemistry. ,vol. 20, pp. 9903- 9909 ,(2010) , 10.1039/C0JM01579B
C. Oliver Kappe, Microwave dielectric heating in synthetic organic chemistry Chemical Society Reviews. ,vol. 37, pp. 1127- 1139 ,(2008) , 10.1039/B803001B
G. Barbarella, M. Melucci, G. Sotgiu, The Versatile Thiophene: An Overview of Recent Research on Thiophene-Based Materials† Advanced Materials. ,vol. 17, pp. 1581- 1593 ,(2005) , 10.1002/ADMA.200402020
Belinda Baisch, Diego Raffa, Ulrich Jung, Olaf M. Magnussen, Cyril Nicolas, Jerome Lacour, Jens Kubitschke, Rainer Herges, Mounting freestanding molecular functions onto surfaces: the platform approach. Journal of the American Chemical Society. ,vol. 131, pp. 442- 443 ,(2009) , 10.1021/JA807923F
Pierpaolo Greco, Massimiliano Cavallini, Pablo Stoliar, Santiago David Quiroga, Soumya Dutta, Stefano Zacchini, Maria Carmela Iapalucci, Vittorio Morandi, Silvia Milita, Pier Giorgio Merli, Fabio Biscarini, Conductive sub-micrometric wires of platinum-carbonyl clusters fabricated by soft-lithography. Journal of the American Chemical Society. ,vol. 130, pp. 1177- 1182 ,(2008) , 10.1021/JA074104M