Alkylation via tris(dialkylamino)sulfonium enolates

作者: R. Noyori , I. Nishida , J. Sakata

DOI: 10.1016/S0040-4039(00)71493-6

关键词:

摘要: Abstract Tris(dialkylamino)sulfonium enolates generated from tris(diethylamino)sulfonium difluorotrimethylsiliconate and enol silyl ethers are readily alkylated by various alkyl halides under mild conditions.

参考文章(9)
M. Julia, Free radical cyclizations, XVII. Mechanistic studies Pure and Applied Chemistry. ,vol. 40, pp. 553- 567 ,(1974) , 10.1351/PAC197440040553
William A. Kleschick, Charles T. Buse, Clayton H. Heathcock, Stereoselection in the aldol condensation Journal of the American Chemical Society. ,vol. 99, pp. 247- 248 ,(1977) , 10.1021/JA00443A046
Alan H Cowley, Donald J Pagel, Michael L Walker, None, Amino-Substituted Sulfonium Salts; Synthesis and Stereochemistry. Journal of the American Chemical Society. ,vol. 100, pp. 7065- 7066 ,(1978) , 10.1021/JA00490A049
Marc Julia, Free-radical cyclizations Accounts of Chemical Research. ,vol. 4, pp. 386- 392 ,(1971) , 10.1021/AR50047A005
Organic Free Radicals Chemical & Engineering News. ,vol. 46, pp. 70- ,(1978) , 10.1021/BK-1978-0069
Isao Kuwajima, Eiichi Nakamura, Quaternary ammonium enolates as synthetic intermediates. Regiospecific alkylation reaction of ketones Journal of the American Chemical Society. ,vol. 97, pp. 3257- 3258 ,(1975) , 10.1021/JA00844A076
R. Noyori, K. Yokoyama, J. Sakata, Isao Kuwajima, Eiichi Nakamura, Makoto Shimizu, Fluoride ion catalyzed aldol reaction between enol silyl ethers and carbonyl compounds Journal of the American Chemical Society. ,vol. 99, pp. 1265- 1267 ,(1977) , 10.1021/JA00446A049
William J. Middleton, New fluorinating reagents. Dialkylaminosulfur fluorides ChemInform. ,vol. 6, pp. 574- 578 ,(1975) , 10.1021/JO00893A007
M. Hanack, H. -J. Schneider, Umlagerungen von Homoallyl-, von Cyclopropylmethyl- und Cyclobutyl-Verbindungen Springer, Berlin, Heidelberg. pp. 554- 607 ,(1967) , 10.1007/BFB0071302