Spectroscopic method for the determination of the electron temperature in quasi-thermal air discharges. Application to an inductively coupled air plasma at atmospheric pressure

作者: Anne-Marie Gomes , Jean-Philippe Sarrette , Lydie Madon , Arnaud Epifanie

DOI: 10.1039/JA9951000923

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摘要: A method for the approximation of electron temperature, θe, in quasi-thermal air discharges, based on measurements relative emissivities weakly resolved OH and NO vibrational bands 210–320 nm spectral range, is described. The very sensitive particularly suitable between 2000 6000 K, where intensities emitted by atomic lines cannot be easily distinguished from molecular bands. It shown that departures thermodynamic equilibrium induced radiative losses or a difference heavy particle θg, lead to large systematic errors as long ratio X=θe:θg stays below 1.2. uncertainty temperature determination discussed together with an application inductively coupled plasma at atmospheric pressure.

参考文章(9)
J.P. Sarrette, A.M. Gomes, J. Bacri, Collisional-radiative modelling of quasi-thermal air plasmas with electronic temperatures between 2000 and 13,000 K—II. 2000 K⩽Θe⩽4000 K Journal of Quantitative Spectroscopy & Radiative Transfer. ,vol. 53, pp. 143- 152 ,(1995) , 10.1016/0022-4073(95)90002-0
Izumi Ishii, Akbar Montaser, A tutorial discussion on measurements of rotational temperature in inductively coupled plasmas Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 46, pp. 1197- 1206 ,(1991) , 10.1016/0584-8547(91)80114-I
John M. Workman, P. A. Fleitz, Harry B. Fannin, Joseph A. Caruso, C. J. Seliskar, A Comparative Study of Rotational Temperatures in a Microwave Plasma: OH Radical versus N2+: Applied Spectroscopy. ,vol. 42, pp. 96- 100 ,(1988) , 10.1366/0003702884428581
B. Raeymaekers, J.A.C. Broekaert, F. Leis, Radially resolved rotational temperatures in nitrogen-argon, oxygen-argon, air-argon and argon ICPs Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 43, pp. 941- 949 ,(1988) , 10.1016/0584-8547(88)80199-X
A Czernichowski, Temperature evaluation from the partially resolved 391 nm N2+ band Journal of Physics D. ,vol. 20, pp. 559- 564 ,(1987) , 10.1088/0022-3727/20/5/001
S. Nowak, J.A.M. Van Der Mullen, D.C. Schram, Electron density and temperature determination in an ICP using a non-equilibrium concept Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 43, pp. 1235- 1245 ,(1988) , 10.1016/0584-8547(88)80166-6
J. P. Sarrette, A. M. Gomes, J. Bacri, C. O. Laux, C. H. Kruger, COLLISIONAL-RADIATIVE MODELLING OF QUASI-THERMAL AIR PLASMAS WITH ELECTRONIC TEMPERATURES BETWEEN 2000 AND 13,000 K. I: THETA E> 4000 K Journal of Quantitative Spectroscopy & Radiative Transfer. ,vol. 53, pp. 125- 141 ,(1995)