Rh(I)-catalyzed [5+1] cycloaddition of vinylcyclopropanes and CO for the synthesis of α,β- and β,γ-cyclohexenones.

作者: Guo-Jie Jiang , Xu-Fei Fu , Qian Li , Zhi-Xiang Yu

DOI: 10.1021/OL2031526

关键词:

摘要: A cationic Rh(I)-catalyzed [5 + 1] cycloaddition of vinylcyclopropanes and CO has been developed, affording either β,γ-cyclohexenones as major products or α,β-cyclohexenones exclusively, under different reaction conditions.

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