Introducing asymmetric functionality into MOFs via the generation of metallic Janus MOF particles.
作者： Abraham Ayala , Carlos Carbonell , Inhar Imaz , Daniel Maspoch
DOI: 10.1039/C6CC01098A
关键词:
摘要: Herein we report a versatile methodology for engineering metallic Janus MOF particles based on desymmetrization at interfaces, whereby each particle is partially coated with desired metal. We demonstrate that it enables the fabrication of homogeneous according to (ZIF-8, UiO-66 or UiO-66-SH), metal (Au, Co Pt), size (from micrometer submicrometer regime) and metal-film thickness 5 nm 50 nm) employed. anticipate our strategy could be applied impart new functionalities MOFs, including asymmetric functionalization, magnetic-guidance motorization.
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