Synthesis and Structures of Oxo-Bridged Distannyl- and Digermyldirhenium Complexes
作者： Richard D. Adams , Burjor Captain , Carl B. Hollandsworth , Mikael Johansson , Jack L. Smith
DOI: 10.1021/OM060375E
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摘要: The reaction of Re2(CO)8(μ-SnPh2)2 (1) with NaOMe in methanol the presence Bun4NBr yielded salt [NBun4][Re2(CO)8{μ-Ph2SnO(Me)SnPh2}] (3). anion 3 contains a Ph2SnO(Me)SnPh2 ligand formed by addition [OMe]- group to two bridging SnPh2 groups 1. bidentate bridges Re(CO)4 that are joined Re−Re single bond. Re2(CO)8[μ-C(H)C(H)Bun](μ-H) Ph3GeH and H2O heptane solvent complex Re2(CO)8[μ-Ph2GeO(H)GePh2](μ-H) (4). structure 4 consists units bridged Ph2GeO(H)GePh2 hydrido Compound was deprotonated at OH treatment [NBun4][OH] give [NBun4][Re2(CO)8(μ-Ph2GeOGePh2)(μ-H)] ([NBun4]·5). three new compounds were characterized IR, 1H NMR, single-crystal X-ray diffraction analyses. electronic structures 5 probed computations employing density functional theory (ADF 2004.01, PW91).
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B. Didillon, J.P. Candy, F. Le Peletier, O.A. Ferretti, J.M. Basset, Surface Organometallic Chemistry on Metals; Selective hydrogenation of citral on silica supported Rhodium modified by tetra-n-butyl Germanium, Tin and Lead Studies in Surface Science and Catalysis. ,vol. 78, pp. 147- 154 ,(1993) , 10.1016/S0167-2991(08)63314-5
Gary L. Rochfort, John E. Ellis, Highly reduced organometallics Journal of Organometallic Chemistry. ,vol. 250, pp. 277- 290 ,(1983) , 10.1016/0022-328X(83)85058-X
Mark S. Holt, William L. Wilson, John H. Nelson, Transition metal-tin chemistry Chemical Reviews. ,vol. 89, pp. 11- 49 ,(1989) , 10.1021/CR00091A002
Richard D. Adams, Jack L. Smith, Rhodium cluster complexes containing bridging phenylgermanium ligands. Inorganic Chemistry. ,vol. 44, pp. 4276- 4281 ,(2005) , 10.1021/IC050372E
Richard D. Adams, Burjor Captain, Jack L. Smith, Michael B. Hall, Chad L. Beddie, Charles Edwin Webster, Superloading of tin ligands into rhodium and iridium carbonyl cluster complexes. Inorganic Chemistry. ,vol. 43, pp. 7576- 7578 ,(2004) , 10.1021/IC0489589
Gwendoline Lafaye, Corina Mihut, Catherine Especel, Patrice Marécot, Michael D. Amiridis, FTIR studies of CO adsorption on Rh-Ge/Al2O3 catalysts prepared by surface redox reactions. Langmuir. ,vol. 20, pp. 10612- 10616 ,(2004) , 10.1021/LA049692L
Pierre Braunstein, Michael Veith, Joël Blin, Volker Huch, New Mono- and Polynuclear Iron Silylene and Stannylene Complexes Organometallics. ,vol. 20, pp. 627- 633 ,(2001) , 10.1021/OM000515Z
Kiyoshi Fukui, Sachiko Nishida, CO gas sensor based on Au–La2O3 added SnO2 ceramics with siliceous zeolite coat Sensors and Actuators B: Chemical. ,vol. 45, pp. 101- 106 ,(1997) , 10.1016/S0925-4005(97)00280-3
J.N Coupé, E Jordão, M.A Fraga, M.J Mendes, A comparative study of SiO2 supported Rh–Sn catalysts prepared by different methods in the hydrogenation of citral Applied Catalysis A-general. ,vol. 199, pp. 45- 51 ,(2000) , 10.1016/S0926-860X(99)00525-6
Louis Versluis, Tom Ziegler, The determination of molecular structures by density functional theory. The evaluation of analytical energy gradients by numerical integration Journal of Chemical Physics. ,vol. 88, pp. 322- 328 ,(1988) , 10.1063/1.454603