Comparative study on morphology of ground sub-bituminus FBC fly ash geopolymeric material

作者: Manisara Eiamwijit , Katavut Pachana , Supranee Kaewpirom , Ubolluk Rattanasak , Prinya Chindaprasirt

DOI: 10.1016/J.APT.2015.04.013

关键词:

摘要: Abstract Fluidized bed coal combustion (FBC) is a clean and environmentally friendly process with low emission of SO 2 NO x to atmosphere. However, fly ash from FBC not suitable for further utilization due the high sulfate glassy phase contents. was ground reduce pore increase specific surface area use as source material in geopolymer. geopolymers different sodium silicate hydroxide (G/N) mass ratios were studied characterized using X-ray diffraction (XRD), scanning electron microscopy energy dispersive spectroscopy (SEM–EDX), Fourier transform infrared spectroscopic (FTIR) techniques. Compressive strength materials also tested. Test results indicated that G/N ratio had significant effect on morphology Low gave geopolymer large amount calcium hydroxide. The mixes increased water glass content dense homogeneous composites. presence resulted formation products which coexisted aluminosilicate products.

参考文章(18)
Harald Günther, NMR spectroscopy: An introduction ,(1980)
Joseph Davidovits, Geopolymer Chemistry and Applications ,(2008)
Valeria F.F Barbosa, Kenneth J.D MacKenzie, Clelio Thaumaturgo, Synthesis and characterisation of materials based on inorganic polymers of alumina and silica: sodium polysialate polymers International Journal of Inorganic Materials. ,vol. 2, pp. 309- 317 ,(2000) , 10.1016/S1466-6049(00)00041-6
Ubolluk Rattanasak, Prinya Chindaprasirt, Influence of NaOH solution on the synthesis of fly ash geopolymer Minerals Engineering. ,vol. 22, pp. 1073- 1078 ,(2009) , 10.1016/J.MINENG.2009.03.022
P. Basu, Combustion of coal in circulating fluidized-bed boilers: a review Chemical Engineering Science. ,vol. 54, pp. 5547- 5557 ,(1999) , 10.1016/S0009-2509(99)00285-7
Prinya Chindaprasirt, Pattanapong Paisitsrisawat, Ubolluk Rattanasak, Strength and resistance to sulfate and sulfuric acid of ground fluidized bed combustion fly ash–silica fume alkali-activated composite Advanced Powder Technology. ,vol. 25, pp. 1087- 1093 ,(2014) , 10.1016/J.APT.2014.02.007
Prinya Chindaprasirt, Ubolluk Rattanasak, Chai Jaturapitakkul, Utilization of fly ash blends from pulverized coal and fluidized bed combustions in geopolymeric materials Cement & Concrete Composites. ,vol. 33, pp. 55- 60 ,(2011) , 10.1016/J.CEMCONCOMP.2010.09.017
W.K.W. Lee, J.S.J. van Deventer, Structural reorganisation of class F fly ash in alkaline silicate solutions Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 211, pp. 49- 66 ,(2002) , 10.1016/S0927-7757(02)00237-6
E Álvarez-Ayuso, X Querol, F Plana, A Alastuey, N Moreno, M Izquierdo, O Font, T Moreno, S Diez, E Vázquez, M Barra, None, Environmental, physical and structural characterisation of geopolymer matrixes synthesised from coal (co-)combustion fly ashes Journal of Hazardous Materials. ,vol. 154, pp. 175- 183 ,(2008) , 10.1016/J.JHAZMAT.2007.10.008
Ubolluk Rattanasak, Prinya Chindaprasirt, Properties of alkali activated silica fume–Al(OH) 3 –fluidized bed combustion fly ash composites Materials and Structures. ,vol. 48, pp. 531- 540 ,(2015) , 10.1617/S11527-014-0413-5