Design and preparation of natural layered silicate/bio-based elastomer nanocomposites with improved dispersion and interfacial interaction
作者： He Qiao , Runguo Wang , Hui Yao , Xiaohui Wu , Weiwei Lei
DOI: 10.1016/J.POLYMER.2015.10.011
关键词:
摘要: Abstract Green nanocomposites consisting of bio-based poly(dibutyl itaconate- ter -isoprene- -4-vinylpyridine) (PDBIIVP) elastomers with different 4-vinylpyridine (4-VP) contents and natural layered silicate montmorillonite (MMT) were prepared by a green latex co-coagulation method. The effects the pyridine groups on interfacial interaction, morphology, performance investigated. Ionic bonding interfaces, which confirmed X-ray photoelectron spectroscopy, introduced to through electrostatic attraction between protonated modified electronegative MMT during PDBIIVP aqueous suspension hydrochloric acid. dispersion interaction improved remarkably, as demonstrated diffraction, transmission electron microscopy, rubber process analyzer (RPA) results swelling tests. mechanical gas barrier properties markedly increasing 4-VP content. For 7.0 wt% 4-VP, addition 10 phr increased tensile strength 730% reduced permeability 71%.
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sci-hub.se 参考文章(61)
Mohamed S. El-Aasser, Peter A. Lovell, Emulsion polymerization and emulsion polymers J. Wiley. ,(1997)
Todd Werpy, Gene Petersen, None, Top Value Added Chemicals from Biomass: Volume I -- Results of Screening for Potential Candidates from Sugars and Synthesis Gas Other Information: PBD: 1 Aug 2004. ,(2004) , 10.2172/15008859
Paul J. Flory, John Rehner, Statistical Mechanics of Cross‐Linked Polymer Networks I. Rubberlike Elasticity The Journal of Chemical Physics. ,vol. 11, pp. 512- 520 ,(1943) , 10.1063/1.1723791
Dan Yang, Ming Tian, Hailan Kang, Yingchao Dong, Haoliang Liu, Yingchun Yu, Liqun Zhang, New polyester dielectric elastomer with large actuated strain at low electric field Materials Letters. ,vol. 76, pp. 229- 232 ,(2012) , 10.1016/J.MATLET.2012.02.084
Gerd H. G. Moe-Behrens, Rene Davis, Karmella A. Haynes, Preparing synthetic biology for the world Frontiers in Microbiology. ,vol. 4, pp. 5- 5 ,(2013) , 10.3389/FMICB.2013.00005
Paul J. Flory, John Rehner, Statistical Mechanics of Cross‐Linked Polymer Networks II. Swelling The Journal of Chemical Physics. ,vol. 11, pp. 521- 526 ,(1943) , 10.1063/1.1723792
Hua Zheng, Yong Zhang, Zonglin Peng, Yinxi Zhang, Influence of clay modification on the structure and mechanical properties of EPDM/montmorillonite nanocomposites Polymer Testing. ,vol. 23, pp. 217- 223 ,(2004) , 10.1016/S0142-9418(03)00097-7
Songqi Ma, Xiaoqing Liu, Yanhua Jiang, Zhaobin Tang, Chuanzhi Zhang, Jin Zhu, Bio-based epoxy resin from itaconic acid and its thermosets cured with anhydride and comonomers Green Chemistry. ,vol. 15, pp. 245- 254 ,(2013) , 10.1039/C2GC36715G
E. J. Garboczi, K. A. Snyder, J. F. Douglas, M. F. Thorpe, Geometrical percolation threshold of overlapping ellipsoids Physical Review E. ,vol. 52, pp. 819- 828 ,(1995) , 10.1103/PHYSREVE.52.819
Th. Willke, K.-D. Vorlop, Biotechnological production of itaconic acid Applied Microbiology and Biotechnology. ,vol. 56, pp. 289- 295 ,(2001) , 10.1007/S002530100685