Thiolated arsenic in natural systems: What is current, what is new and what needs to be known.

摘要: Abstract Thiolated arsenic compounds are the sulfur analogous substructures of oxo-arsenicals as arsinoyl (As = O) is substituted by an arsinothioyl (As = S) group. Relatively brief history thioarsenic research, mostly in current decade has endeavored to understand their consequences natural environment. However, related aspects have far not attached much research concern on global scale compared other species. This review attempts provide a critical overview for first time formation mechanisms thioarsenicals, chemistry, speciation and analytical methodologies order rational assessment what new, current, needs be known or should done future research. Thioarsenic play vital role determining biogeochemistry sulfidic environments under reducing conditions. species widely immobilized naturally occurring processes such adsorption iron (oxyhydr)oxides precipitation sulfide minerals. Accurate measurement challenging task due instability upon pH, temperature, redox potential, concentrations oxygen, iron. Assessment direct indirect effects toxic population those who frequently get exposed high levels urgent necessity. Dimethylmonothioarsinic acid (DMMTA V ) most cytotoxic metabolite having similar toxicological dimethylarsinous (DMA III human animal tissues. The chemical analysis thioarsenicals soil sediments highly unknown. Therefore, more inclined towards molecular structure unknown complexes various environmental suites. Contemporary approaches hyphenated existing technologies would pave way overcome challenges standards synthesis, structural determination, quantification sample preservation