Facile synthesis of a conjugated microporous polymeric monolith via copper-free Sonogashira–Hagihara cross-coupling in water under aerobic conditions
作者： Jie Liu , John M. Tobin , Zhengtao Xu , Filipe Vilela
DOI: 10.1039/C5PY00772K
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摘要: A conjugated microporous polymer was synthesized via a modified Sonogashira–Hagihara cross-coupling reaction under aerobic conditions in water and in the absence of copper. These conditions allowed the directing of the CMP format during synthesis into a monolithic structure. Post-modification of the polymer with thiol–yne chemistry followed by AgI uptake led to a catalytically active material for a heterocyclization reaction.
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