Hydroformylation process and catalyst

作者: J Allen

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摘要: 1. IN A HYDROFORMYLATION PROCESS WHICH AN OLEFIN IS REACTED WITH CARBON MONOXIDE AND HYDROGEN UNDER CONDITIONS; THE IMPROVEMENT COMPRISES CARYING OUT REACTION CONDITIONS PRESENCE OF CATALYST PRODUCED BY CONTACTING SOLID PHOSPHORUS-CONTAINING POLYMER AT LEAST ONE PHOSPHINE FORMULA ((R'')2-P-),(R(5-N)-),(H2C=CH)N-BENZENE WHEREIN EACH R OR ALKYL GROUP HAVING 1 TO 4 ATOMS, TOTAL NUMBER ATOMS ALL SUBSTITUENTS BEING 12 LESS, R'' HYDROCARBYL RADICAL SELECTED FROM ALKYL, CYCLOALKYL, ARYL COMBINATIONS THEREOF, SAID CONTAINING 20 N 3, METAL CARBONYL CONSISTING COBALT, RHODIUM, RUTHENIUM, PLATINUM PALLADIUM, PRESENT AMOUNT RANGE 0.2 MILLIMOLE PER 5 GRAMS SUPPORT.

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