Fundamental Reaction Mechanisms in Radiation Chemistry and Recent Examples

作者: Mamoru Fujitsuka , Tetsuro Majima

DOI: 10.1007/978-3-319-09216-4_1

关键词:

摘要: By using radiation chemical methods, such as γ-ray radiolysis and pulse radiolysis, powerful oxidative reductive reagents, which are not available with other can be generated to promote various reactions. The reaction pathways caused by these reagents followed spectroscopic transient absorption EPR. Therefore, methods applicable systems in a wide variety of fields. For example, our research group has studied the mechanisms phenomena means methods. In present chapter, fundamental chemistry introduced initial part. Additionally, investigations on charge delocalization process, radical ions excited state, photocatalytic systems, emitting device, biological examples applicability

参考文章(55)
優 塩谷, A. Lund, Radical ionic systems : properties in condensed phases Kluwer Academic Publishers. ,(1991)
米穂 田畑, 泰男 伊藤, CRC handbook of radiation chemistry CRC Press. ,(1991)
Charles E Swenberg, Martin Pope, Electronic Processes in Organic Crystals and Polymers ,(1999)
Bernd Giese, Jérôme Amaudrut, Anne-Kathrin Köhler, Martin Spormann, Stephan Wessely, Direct observation of hole transfer through DNA by hopping between adenine bases and by tunnelling Nature. ,vol. 412, pp. 318- 320 ,(2001) , 10.1038/35085542
Kiyohiko Kawai, Tadao Takada, Sachiko Tojo, Nobuyuki Ichinose, Tetsuro Majima, Observation of Hole Transfer through DNA by Monitoring the Transient Absorption of Pyrene Radical Cation Journal of the American Chemical Society. ,vol. 123, pp. 12688- 12689 ,(2001) , 10.1021/JA0158152
Akito Ishida, Masayuki Fukui, Hiromitsu Ogawa, Sachiko Tojo, Tetsuro Majima, Setsuo Takamuku, LIFETIMES AND TRANSIENT PHENOMENA OF STILBENE RADICAL CATIONS IN THE SECOND EXCITED DOUBLET STATE The Journal of Physical Chemistry. ,vol. 99, pp. 10808- 10814 ,(1995) , 10.1021/J100027A021
Eric Meggers, Maria E. Michel-Beyerle, Bernd Giese, Sequence Dependent Long Range Hole Transport in DNA Journal of the American Chemical Society. ,vol. 120, pp. 12950- 12955 ,(1998) , 10.1021/JA983092P
Shingo Samori, Mamoru Fujitsuka, Tetsuro Majima, Photodissociation of pyrene dimer radical cation during the pulse radiolysis–laser flash photolysis combined method Research on Chemical Intermediates. ,vol. 39, pp. 449- 461 ,(2013) , 10.1007/S11164-012-0662-2
Kiyohiko Kawai, Kei Miyamoto, Sachiko Tojo, Tetsuro Majima, Formation of Pyrene Dimer Radical Cation in DNA Reflecting DNA Dynamics in the Time Range of 1 μs to 1 ms Journal of the American Chemical Society. ,vol. 125, pp. 912- 915 ,(2003) , 10.1021/JA026754Q
Sadayuki Asaoka, Norihiko Takeda, Tomokazu Iyoda, Andrew R. Cook, John R. Miller, Electron and hole transport to trap groups at the ends of conjugated polyfluorenes. Journal of the American Chemical Society. ,vol. 130, pp. 11912- 11920 ,(2008) , 10.1021/JA800426Z