Coordination Chemistry of Acrylamide 1. Cobalt(II) Chloride Complexes with Acrylamide Synthesis and Crystal Structures
作者： K. B. Girma , Volker Lorenz , Steffen Blaurock , Frank T. Edelmann
关键词:
摘要: Abstract. The molecular structures of blue dichloro-tetrakis(acryl-amide)cobalt(II), [Co{ O -OC(NH 2 )CH CH } 4 Cl ]( 1 ) and pinkhexakis(acrylamide)cobalt(II) tetrachlorocobaltate(II), -OC-(NH 6 ][CoCl ), characterized by single X-ray dif-fraction, IR spectroscopy elemental analyses, are described.The coordination Co II in involves a tetragonally distorted octa-hedral structure with four O-donor atoms acrylamide the Introduction chemistry (AAm CHC(O)NH transition metals is interest dueto biological relevance amide group peptidesand proteins [1 3] context recent public con-cerns on exposure from food its health ef-fects [4]. From industrial point view, ligand isconsidered as an invaluable monomer employed pro-duction water-soluble polymers copolymers that areused numerous applications.Transition metal complexes generallyprepared either direct reaction saltwith or base-catalyzed hydrolysis coordi-nated acrylonitrile [5]. Metal co-ordinating through carbonyl oxygen atom known inseveral cases [5 10]. Complexation throughthe nitrogen Mn
sci-hub.se 参考文章(20)
S. I. Evstratova, G. V. Shilov, G. I. Dzhardimalieva, A. D. Pomogailo, I. E. Uflyand, S. M. Aldoshin, Copper(II) Nitrate Complex with Acrylamide: Synthesis and Crystal Structure ,(2001) , 10.1023/A:1012362511561
Robert W. Hay, Norman Govan, Angelo Perotti, Oliviero Carugo, Copper(II), nickel(II) and palladium(II) complexes of the diamide ligand N,N′-bis(2-carbamoylethyl)ethylenediamine (H2L) and the crystal structure of the carbonyl-oxygen-bonded copper(II) complex [Cu(H2L)](ClO4)2 Transition Metal Chemistry. ,vol. 22, pp. 389- 394 ,(1997) , 10.1023/A:1018574204903
F. Albert Cotton, Advanced Inorganic Chemistry ,(1999)
J. A. Davies, F. R. Hartley, Complexes of the platinum metals containing weak donor ligands Chemical Reviews. ,vol. 81, pp. 79- 90 ,(1981) , 10.1021/CR00041A004
J. Reedijk, Acrylamide, an oxygen-donor ligand to divalent transition-metal ions Inorganica Chimica Acta. ,vol. 5, pp. 687- 690 ,(1971) , 10.1016/S0020-1693(00)96010-9
Patricia M. Angus, David P. Fairlie, W. Gregory Jackson, Synthesis, solution structure, and reactivity of oxygen-bound amides on cobalt(III) Inorganic Chemistry. ,vol. 32, pp. 450- 459 ,(1993) , 10.1021/IC00056A018
V. S. Savost'yanov, V. I. Ponomarev, A. D. Pomogailo, B. S. Seienova, I. N. Ivleva, A. G. Starikov, L. O. Atovmyan, PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS. 14. COMPOSITION AND STRUCTURE OF ACRYLAMIDE COMPLEXES OF TRANSITION METALS Russian Chemical Bulletin. ,vol. 39, pp. 674- 679 ,(1990) , 10.1007/BF00960324
David P. Fairlie, Patricia M. Angus, M. David. Fenn, W. Gregory. Jackson, Factors Influencing the Nitrogen Vs Oxygen Bonding Mode of Amides Bound to Pentaamminecobalt(Iii) and the Kinetics and Mechanism of Rearrangement Inorganic Chemistry. ,vol. 30, pp. 1564- 1569 ,(1991) , 10.1021/IC00007A026
I. E. Uflyand, A. G. Starikov, V. S. Savost'yanov, A. D. Pomogailo, Preparation and reactivity of metal-containing monomers. 17. Spatial and electronic structure of complexes of cobalt nitrate and chloride with acrylamide Russian Chemical Bulletin. ,vol. 39, pp. 1185- 1189 ,(1990) , 10.1007/BF00962381
R.A. Kydd, A.P.C. Dunham, The infrared spectra and structure of acetamide and acrylamide Journal of Molecular Structure. ,vol. 69, pp. 79- 88 ,(1980) , 10.1016/0022-2860(80)85266-5