ON THE WAY TO HEPTAHEXAENYLIDENE COMPLEXES : TRAPPING OF AN INTERMEDIATE WITH THE NOVEL M=C=C=C=C=C=C=CR2 MOIETY
作者： Gerhard Roth , Helmut Fischer
DOI: 10.1021/OM960605X
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摘要: Sequential treatment of the in situ generated heptatriyne Me3SiC⋮CC⋮CC⋮CC(NMe2)3 with n-BuLi, (CO)5W[THF], and BF3·OEt2 affords first alkenyl-substituted pentatetraenylidene complex, (CO)5WC CCCC(NMe2)C(H)C(NMe2)2 (4), via addition dimethylamine to CeCζ bond intermediate heptahexaenylidene complex (CO)5WCαCβCγCδ CeCζCη(NMe2)2. In addition, alkynyl(butatrienyl)carbene (CO)5WC(C⋮CSiMe3)C(Bu)C CC(NMe2)2 (5) is formed.
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Helmut Fischer, David Reindl, Gerhard Roth, Eine effiziente Synthesemethode für DiarylallenyIiden(pentacarbonyl)chrom- und -wolfram-Komplexe -Kristallstruktur von (CO)5Cr=C=C=CPh2 / An efficient Synthesis of Diarylallenylidene Pentacarbonyl Chromium and Tungsten Complexes - Crystal Structure of (CO)5Cr=C=C=CPh2 Zeitschrift für Naturforschung B. ,vol. 49, pp. 1207- 1214 ,(1994) , 10.1515/ZNB-1994-0909
Nathalie Le Narvor, Loic Toupet, Claude Lapinte, ELEMENTAL CARBON CHAIN BRIDGING TWO IRON CENTERS: SYNTHESES AND SPECTROSCOPIC PROPERTIES OF [CP(DPPE) FE-C4- FECP(DPPE)]N+.CNTDOT.N[PF6]-. X-RAY CRYSTAL STRUCTURE OF THE MIXED VALENCE COMPLEX (N = 1) Journal of the American Chemical Society. ,vol. 117, pp. 7129- 7138 ,(1995) , 10.1021/JA00132A013
Willi Kantlehner, Erwin Haug, Walter W. Mergen, Peter Speh, Thomas Maier, Joanis J. Kapassakalidis, H. J. Bräuner, Helmut Hagen, Ein Herstellungsverfahren für N,N,N′, N′,N″,N″ - Hexaalkylguanidinium-chloride Synthesis. ,vol. 1983, pp. 904- 905 ,(1983) , 10.1055/S-1983-30558
Wolfgang Beck, Burkhard Niemer, Michael Wieser, Methoden zur Synthese von (μ‐Kohlenwasserstoff)‐Übergangsmetallkomplexen ohne Metall‐Metall‐Bindung Angewandte Chemie. ,vol. 105, pp. 969- 996 ,(1993) , 10.1002/ANGE.19931050704
Jeffry S. Schumm, Darren L. Pearson, James M. Tour, Synthese linearer konjugierter Oligomere mit einer iterativen, divergenten/konvergenten Methode zur Verdopplung der Monomereinheiten: ein rascher Zugang zu einem 128 Å langen, potentiell leitenden molekularen Draht Angewandte Chemie. ,vol. 106, pp. 1445- 1448 ,(1994) , 10.1002/ANGE.19941061322
Daniel Touchard, Pierre Haquette, Alain Daridor, Loiec Toupet, Pierre H. Dixneuf, First Isolable Pentatetraenylidene Metal Complex Containing the Ru:C:C:C:C:CPh2 Assembly. A Key Intermediate To Provide Functional Allenylidene Complexes Journal of the American Chemical Society. ,vol. 116, pp. 11157- 11158 ,(1994) , 10.1021/JA00103A041
Anne-Marie Giroud-Godquin, Peter M. Maitlis, Metallomesogene: Metallkomplexe in geordneten fluiden Phasen Angewandte Chemie. ,vol. 103, pp. 370- 398 ,(1991) , 10.1002/ANGE.19911030405
Nathalie Le Narvor, Claude Lapinte, First C4 bridged mixed-valence iron(II)–iron(III) complex delocalized on the infrared timescale Journal of The Chemical Society, Chemical Communications. pp. 357- 359 ,(1993) , 10.1039/C39930000357
Antonio Romero, Angel Vegas, Pierre H. Dixneuf, Cumulene mit Ruthenium: Bildung von 2,3,4-Pentatrienyliden- und 3-Oxo-1,4-pentadienyl-Komplexen† Angewandte Chemie. ,vol. 102, pp. 210- 211 ,(1990) , 10.1002/ANGE.19901020220
Gerhard Roth, Helmut Fischer, Complexes with Diamino-Substituted Unsaturated C3 and C5 Ligands: First Group 6 Pentatetraenylidenes and New Allenylidene Complexes Organometallics. ,vol. 15, pp. 1139- 1145 ,(1996) , 10.1021/OM950845X