Wide-temperature range operation supercapacitors from nanostructured activated carbon fabric

作者: Kaihsuan Hung , Charan Masarapu , Tsehao Ko , Bingqing Wei

DOI: 10.1016/J.JPOWSOUR.2009.01.083

关键词:

摘要: Abstract Electrochemical power sources that offer high energy and densities and, can also withstand a harsh temperature range have become extremely desirable in applications ranging from civilian portable electronic devices to military weapons. In this report, we demonstrated wide withstanding supercapacitor which be operated 100 °C −40 °C within voltage window −2 V 2 V. The performance of the coin cells, assembled with nanostructured activated carbon fabric (ACF) as electrode material 1 M tetraethylammonium tetrafluoroborate (TEABF 4 ) polypropylene carbonate (PC) solution electrolyte, was systematically studied set window. ACF yielded ideal rectangular shapes cyclic voltammograms 0–100 °C an average mass capacitance 90 F g −1 60 F g at −25 °C. still over 20 F g low −40 °C. Another exciting feature supercapacitors they resumed their room when cooled defrosted −40 °C, demonstrating excellent repeatability stability. charge–discharge behavior showed long-cycle stability extreme temperatures. These electrochemical performances make type very promising many practical applications.

参考文章(15)
Tse-Hao Ko, P. chiranairadul, Chiu-Kuang Lu, Chung-Hua Lin, The effects of activation by carbon dioxide on the mechanical properties and structure of PAN-based activated carbon fibers Carbon. ,vol. 30, pp. 647- 655 ,(1992) , 10.1016/0008-6223(92)90184-X
John Chmiola, G Yushin, Yury Gogotsi, Christele Portet, Patrice Simon, Pierre-Louis Taberna, Anomalous Increase in Carbon Capacitance at Pore Sizes Less Than 1 Nanometer Science. ,vol. 313, pp. 1760- 1763 ,(2006) , 10.1126/SCIENCE.1132195
Hang Shi, Activated carbons and double layer capacitance Electrochimica Acta. ,vol. 41, pp. 1633- 1639 ,(1996) , 10.1016/0013-4686(95)00416-5
Raymond Jasinski, Susan Carroll, Thermal Stability of a Propylene Carbonate Electrolyte Journal of The Electrochemical Society. ,vol. 117, pp. 218- 219 ,(1970) , 10.1149/1.2407468
T. Morimoto, K. Hiratsuka, Y. Sanada, K. Kurihara, Electric double-layer capacitor using organic electrolyte Journal of Power Sources. ,vol. 60, pp. 239- 247 ,(1996) , 10.1016/S0378-7753(96)80017-6
X.H. Li, Y.Z. Meng, Q. Zhu, S.C. Tjong, Thermal decomposition characteristics of poly(propylene carbonate) using TG/IR and PY-GC/MS techniques Polymer Degradation and Stability. ,vol. 81, pp. 157- 165 ,(2003) , 10.1016/S0141-3910(03)00085-5
Rüdiger Kötz, MJEA Carlen, Principles and applications of electrochemical capacitors Electrochimica Acta. ,vol. 45, pp. 2483- 2498 ,(2000) , 10.1016/S0013-4686(00)00354-6
Rüdiger Kötz, Matthias Hahn, Roland Gallay, Temperature behavior and impedance fundamentals of supercapacitors Journal of Power Sources. ,vol. 154, pp. 550- 555 ,(2006) , 10.1016/J.JPOWSOUR.2005.10.048
A.G. Pandolfo, A.F. Hollenkamp, Carbon properties and their role in supercapacitors Journal of Power Sources. ,vol. 157, pp. 11- 27 ,(2006) , 10.1016/J.JPOWSOUR.2006.02.065