Light‐Sensitive and Recoverable N‐Heterocyclic Carbene Copper(I) Complex in Homogeneous Catalysis
作者： Guodong Zhang , Rui Lang , Wenlong Wang , Hui Lv , Liyuan Zhao
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摘要: The synthesis of a light-responsive N-heterocyclic carbene copper(I) complex by introducing nitrobenzospiropyran unit into the ligand was developed. solubility this controlled through reversible conversion between its netural and ionic states using ultraviolet light irradiation. Taking advantage such light-sensitive property facilitated recovery reuse in copper(I)-catalyzed homogeneous oxidation "click" reactions.
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