A Chemical and Theoretical Way to Look at Bonding on Surfaces.

作者: Roald Hoffmann

DOI: 10.1103/REVMODPHYS.60.601

关键词:

摘要: … The surface and bulk acting as a reservoir of electrons or holes at the Fermi level are important in this context. Chemisorption emerges as a compromise in a continuum of bonding …

参考文章(95)
Alfred B. Anderson, S.P. Mehandru, Acetylene adsorption to Fe(100), (110), and (111) surfaces; structures and reactions Surface Science. ,vol. 136, pp. 398- 418 ,(1984) , 10.1016/0039-6028(84)90620-4
Wanda Andreoni, C. M. Varma, Binding and dissociation of CO on transition-metal surfaces Physical Review B. ,vol. 23, pp. 437- 444 ,(1981) , 10.1103/PHYSREVB.23.437
J. Andzelm, D. R. Salahub, Chemisorption of CO on Pd(100): An lcgto‐lsd cluster study International Journal of Quantum Chemistry. ,vol. 29, pp. 1091- 1104 ,(1986) , 10.1002/QUA.560290508
Ph. Avouris, P.S. Bagus, C.J. Nelin, Unfilled levels and excited states of adsorbates on metal surfaces Journal of Electron Spectroscopy and Related Phenomena. ,vol. 38, pp. 269- 287 ,(1986) , 10.1016/0368-2048(86)85098-8
R. C. Baetzold, Interaction of saturated hydrocarbons with transition-metal films: molecular orbital calculations Journal of the American Chemical Society. ,vol. 105, pp. 4271- 4276 ,(1983) , 10.1021/JA00351A026
W.F. Banholzer, Y.O. Park, K.M. Mak, R.I. Masel, A model for the plane to plane variations in catalytic activity seen during nitric oxide decomposition on platinum Surface Science. ,vol. 128, pp. 176- 190 ,(1983) , 10.1016/S0039-6028(83)80025-9
U Bardi, D Dahlgren, PN Ross, Structure and chemisorptive properties of the Pt3Ti surface Journal of Catalysis. ,vol. 100, pp. 196- 209 ,(1986) , 10.1016/0021-9517(86)90085-0
Carsten Benndorf, Bernd Krüger, Fritz Thieme, Surface science lettersUnusually low stretching frequency for CO adsorbed on Fe(100) Surface Science. ,vol. 163, ,(1985) , 10.1016/0039-6028(85)90842-8
B. Bigot, C. Minot, Extended Huckel study of the metallic growth of small platinum clusters: structure and energetics Journal of the American Chemical Society. ,vol. 106, pp. 6601- 6615 ,(1984) , 10.1021/JA00334A026