Hydrogen from bottle-the magic of Pt catalysts for methanol reforming instantly start-up from cold weather

作者: Yongxiang Zhao , Yu Huang , Pengfei Gao , Haoyi Chen , Sergio Gonzalez-Cortes

DOI: 10.1016/J.IJHYDENE.2016.04.202

关键词:

摘要: Abstract Hydrogen is a clean energy carrier, but does not occur naturally. Here we reported novel process to get instant hydrogen from mixture of methanol and dilute peroxide. The can be obtained instantly once the fuel in contact with platinum catalyst without any external heating or input. started stopped more than 100 times before new load required. Pure produced by combining reforming water gas shift bed, which driven heat process. Interestingly discovered that only catalysts synergistically activate peroxide give spontaneously. preparation conditions impurities have significant effects on This work overcomes various hurdles on-board for production provides way catalyse utilization cells.

参考文章(31)
Ahmet K Avcı, Z İlsen Önsan, David L Trimm, On-board hydrogen generation for fuel cell-powered vehicles: the use of methanol and propane Topics in Catalysis. ,vol. 22, pp. 359- 367 ,(2003) , 10.1023/A:1023504826480
Ludwig Jörissen, Holger Klos, Peter Lamp, Gudrun Reichenauer, Victor Trapp, Hydrogen storage in carbon materials—preliminary results The 12th international winterschool on electronic properties of novel materials: progress in molecular nanostructures. ,vol. 442, pp. 481- 484 ,(2008) , 10.1063/1.56436
Y. Zhai, D. Pierre, R. Si, W. Deng, P. Ferrin, A. U. Nilekar, G. Peng, J. A. Herron, D. C. Bell, H. Saltsburg, M. Mavrikakis, M. Flytzani-Stephanopoulos, Alkali-stabilized Pt-OHx species catalyze low-temperature water-gas shift reactions. Science. ,vol. 329, pp. 1633- 1636 ,(2010) , 10.1126/SCIENCE.1192449
Osman Sinan Süslü, İpek Becerik, On-Board Fuel Processing for a Fuel Cell−Heat Engine Hybrid System† Energy & Fuels. ,vol. 23, pp. 1858- 1873 ,(2009) , 10.1021/EF8003575
D.J. Durbin, C. Malardier-Jugroot, Review of hydrogen storage techniques for on board vehicle applications International Journal of Hydrogen Energy. ,vol. 38, pp. 14595- 14617 ,(2013) , 10.1016/J.IJHYDENE.2013.07.058
Andrew F. Dalebrook, Weijia Gan, Martin Grasemann, Séverine Moret, Gábor Laurenczy, Hydrogen storage: beyond conventional methods Chemical Communications. ,vol. 49, pp. 8735- 8751 ,(2013) , 10.1039/C3CC43836H
Hervé Barthélémy, Hydrogen storage – Industrial prospectives International Journal of Hydrogen Energy. ,vol. 37, pp. 17364- 17372 ,(2012) , 10.1016/J.IJHYDENE.2012.04.121
G. A. Petrachi, G. Negro, S. Specchia, G. Saracco, P. L. Maffettone, V. Specchia, Combining Catalytic Combustion and Steam Reforming in a Novel Multifunctional Reactor for On-Board Hydrogen Production from Middle Distillates Industrial & Engineering Chemistry Research. ,vol. 44, pp. 9422- 9430 ,(2005) , 10.1021/IE050215N
A. Vojvodic, J. K. Nørskov, F. Abild-Pedersen, Electronic Structure Effects in Transition Metal Surface Chemistry Topics in Catalysis. ,vol. 57, pp. 25- 32 ,(2014) , 10.1007/S11244-013-0159-2
Sunita Satyapal, John Petrovic, Carole Read, George Thomas, Grace Ordaz, The U.S. Department of Energy's National Hydrogen Storage Project: Progress towards meeting hydrogen-powered vehicle requirements Catalysis Today. ,vol. 120, pp. 246- 256 ,(2007) , 10.1016/J.CATTOD.2006.09.022